AQUEOUS COSMETIC COMPOSITION COMPRISING ALKYLCELLULOSE, AT LEAST ONE NON-VOLATILE OIL, A HYDROCARBON

专利摘要:
The present invention relates to a cosmetic composition in the form of an emulsion of an oil-in-water emulsion comprising: (A) at least 5% by weight of water relative to the total weight of the composition; (B) alkylcellulose, the alkyl residue of which has 2 to 6 carbon atoms; (C) at least one non-volatile hydrocarbon or silicone oil; (D) at least one hydrocarbon resin of average molecular weight less than or equal to 10,000 g / mol. It also relates to a process for makeup and / or care of the lips in which the above-mentioned composition is applied.
公开号:FR3037794A1
申请号:FR1555981
申请日:2015-06-26
公开日:2016-12-30
发明作者:Nowak Virginie Perez；Nathalie Julien
申请人:LOreal SA；
IPC主号:

专利说明:

[0001] The subject of the present invention is cosmetic compositions, in particular dedicated to the makeup and / or care of keratinous substances, in particular for the lips. DESCRIPTION OF PREFERRED EMBODIMENTS These compositions are in the form of an emulsion, comprising water, alkylcellulose, at least one hydrocarbon-based, fluorinated or silicone nonvolatile oil, and at least one low molecular weight hydrocarbon resin. These compositions make it possible to obtain a deposit, in particular of make-up, having good cosmetic properties, in particular in terms of hold, gloss, comfort and absence of tack. The cosmetic compositions for makeup and / or care of keratin materials are in particular in the form of more or less viscous liquids or solids. They have to respond to very particular characteristics making it possible on the one hand to guarantee their storage stability (to avoid dephasing or the exudation of ingredients) and on the other hand to guarantee good properties of use, such as ease of use. application and good cosmetic properties of the film thus obtained.
[0002] These compositions must therefore have a suitable viscosity to prevent sagging in the case of fluid compositions. And in the case of solid compositions, their consistency must be compatible with a solid structure not breaking the application and with a capacity to disintegrate sufficiently to allow the deposition of the composition in an appropriate amount.
[0003] In addition to these criteria, the resulting deposit must also have good use properties such as giving a comfortable, non-tacky, homogeneous deposit with good color fastness, gloss or matte characteristics, for example. Most of the makeup compositions and / or care of the lips currently on the market are anhydrous compositions but recently there is a rise in aqueous compositions for lip makeup. For example, application FR 2964868 describes cosmetic compositions in emulsion form, comprising water and nonvolatile, silicone and / or hydrocarbon oils, and ethylcellulose. Such compositions have the advantages of being homogeneous, stable over time (for example, there is no evidence of exudation or phase shift, especially after 1 month at room temperature). They are easy to apply on the skin and / or the lips and bring an unusual feeling of freshness for this type of compositions, in particular when they are intended to be applied to the lips. The deposit obtained is moreover, thin and light, homogeneous, with good properties in terms of gloss, absence or limitation of tack.
[0004] However, it is desirable to further increase the color fastness of the deposit obtained, particularly resistant to the consumption of food or drink. The present invention is specifically intended to meet these needs. Thus, according to a first of its aspects, the present invention relates to a cosmetic composition in the form of an emulsion comprising: (A) at least 5% by weight of water relative to the total weight of the composition; (B) alkylcellulose, the alkyl residue of which has 2 to 6 carbon atoms; (C) at least one hydrocarbon, fluorinated or non-volatile silicone oil; (D) at least one hydrocarbon resin having a number average molecular weight less than or equal to 10,000 g / mol. The composition according to the invention makes it possible to significantly improve the resistance of the color of the deposit without losing its good properties of comfort, absence of tack, gloss. The composition is also very stable in storage.
[0005] It has also been found that the composition still applies as easily and allows to lead to makeup with precise contours of the lips, which remains over time. In addition, the deposit obtained remains fine, homogeneous, with this original impression of freshness to the application. But other advantages of the invention will be apparent from reading the description 20 and non-limiting examples that follow. The composition according to the invention is more particularly in liquid form. For the purposes of the present invention, the term "liquid" (or "fluid") is intended to mean a composition capable of flowing under its own weight at ambient temperature (at 20 ° C.) and at atmospheric pressure (760 mm). of Hg), as opposed to solid. In particular, "liquid" means a fluid texture, that is to say can be in particular in creamy or pasty form. Protocol for measuring viscosity: The measurement of the viscosity is generally carried out at 20 ° C., using a RHEOMAT RM 180 viscometer equipped with a No. 2, No. 3 or No. 4 rotor, the measurement being carried out after 10 minutes of rotation of the mobile within the composition (time at which time a stabilization of the viscosity and the speed of rotation of the mobile) is observed, at a shear of 200 revolutions / min (rpm).
[0006] Preferably, the composition according to the invention may have a viscosity at 25 ° C. of between 0.1 and 25 Pa.s, preferably of between 0.2 and 20 Pa.s. Preferably, the viscosity at 25 ° C of a composition according to the invention may be between 0.2 and 10 Pa.s.
[0007] In particular, the viscosity at 25 ° C of a composition according to the invention may be between 0.1 Pa.s (mobile 2) and 25 Pa.s (mobile 4), preferably between 0.2 Pa .s (mobile 2) at 20 Pa.s (mobile 4), and better between 0.2 Pa.s (mobile 2) to 10 Pa.s (mobile 4). Thus the compositions according to the invention are liquid compositions dedicated to the makeup and / or care of keratin materials, in particular the skin and / or the lips, and better the lips. These compositions are in the form of compositions comprising at least one emulsion, preferably oil-in-water, or even compositions in the form of oil-in-water emulsions.
[0008] Preferably, the cosmetic composition according to the invention is a lipstick, in particular a liquid, or a gloss for the lips. According to another of its aspects, the subject of the present application is a cosmetic process for makeup and / or care of keratinous substances, in particular lips and / or skin, and better still lips, comprising at least one step consisting of to apply on said keratinous materials at least one composition as defined above. ALKYLCELLULOSE As indicated above, the composition according to the invention comprises at least alkylcellulose whose alkyl residue comprises between 2 and 6 carbon atoms, especially between 2 and 3 carbon atoms. According to a particular embodiment, the previously defined alkylcellulose, and preferably ethylcellulose, represents a content ranging from 1 to 20% by weight, relative to the weight of the composition; the weight of ethylcellulose being expressed as solids. Preferably, the composition according to the invention may comprise from 4 to 20% by weight, expressed as dry alkylcellulose, more particularly from 5 to 15% by weight, expressed as dry alkylcellulose, relative to the total weight of said composition.
[0009] The alkylcellulose is a cellulose alkyl ether comprising a chain consisting of 3-anhydroglucose units linked together by acetal bonds, each anhydroglucose unit having three replaceable hydroxyl groups, all or part of these hydroxyl groups being able to react according to the following reaction: RONa + R'Cl ROR '+ NaCl, where R represents a cellulose radical and R' represents a C2-C6 alkyl radical Advantageously, the alkylcellulose may be chosen from ethylcellulose and propylcellulose According to a particularly preferred embodiment, the alkylcellulose may be ethylcellulose.
[0010] It is an ethyl cellulose ether. The total substitution of the three hydroxyl groups would lead for each anhydroglucose unit to a degree of substitution of 3, in other words to an alkoxy content of 54.88%.
[0011] The ethylcellulose polymers used in a cosmetic composition according to the invention are preferably polymers having a degree of substitution in ethoxy groups ranging from 2.5 to 2.6 per anhydroglucose unit, in other words comprising an ethoxy group content ranging from 44 to 50%. The alkylcellulose may be used in the form of a powder, such as, for example, Dow Chemicals ETHOCEL Standard products. According to a preferred embodiment, the alkylcellulose (preferably ethylcellulose) may be used in a composition of the invention in the form of particles dispersed in an aqueous phase, like a latex-type dispersion or pseudolatex. The techniques for preparing these latex dispersions are well known to those skilled in the art. Particularly suitable as the aqueous dispersion of ethylcellulose, the product marketed by FMC Biopolymer under the name "AQUACOAT ECD-30", which consists of a dispersion of ethylcellulose at a rate of about 26.2% by weight in the water and stabilized with sodium lauryl sulfate and cetyl alcohol. According to a particular embodiment, the aqueous dispersion of ethylcellulose, in particular the "AQUACOAT ECD" product, may be used in amounts of 10 to 90% by weight, in particular 15 to 60% by weight, preferably from 15 to 45% by weight of ethylcellulose dispersion, relative to the total weight of the composition.
[0012] PHYSIOLOGICALLY ACCEPTABLE MEDIUM In addition to the compounds indicated above, the composition according to the invention comprises a physiologically acceptable medium. By "physiologically acceptable medium" is meant a medium which is particularly suitable for the application of a composition of the invention to keratin materials, in particular the skin and / or the lips, such as water and the different oils. of those indicated above or organic solvents commonly used in cosmetic compositions. The physiologically acceptable medium (acceptable tolerance, toxicology, and feel) is generally adapted to the nature of the carrier to which the composition is to be applied, as well as to the appearance under which the composition is to be packaged. NON-VOLATILE OILS HYDROCARBONES, FLUORES OR SILICONES As indicated above, the composition according to the invention comprises at least one non-volatile oil hydrocarbon, fluorinated or silicone, and mixtures thereof.
[0013] According to a preferred embodiment of the invention, the composition comprises at least one first non-volatile hydrocarbon oil which will be defined below and at least one additional oil chosen from non-volatile silicone oils, among the oils. non-volatile fluorinated, among the non-volatile hydrocarbon oils 5 (second oils), polar or apolar, alone or in mixtures. By "oil" is meant a non-aqueous compound, not giving a stable mixture with water, liquid at room temperature (25 ° C) and atmospheric pressure (1.013 .105 Pa). By "non-volatile" is meant an oil whose vapor pressure at 25 ° C. and atmospheric pressure is non-zero and less than 0.02 mm Hg (2.66 Pa) and better still less than 10 -3 mm. Hg (0.13 Pa). FIRST NON-VOLATILE OILS Thus, the composition according to the invention comprises at least one first particular non-volatile hydrocarbon oil. The latter is chosen from: - C10-C26 alcohols, preferably monoalcohols; More particularly, the C 10 -C 26 alcohols are saturated or unsaturated, branched or unbranched, and comprise from 10 to 26 carbon atoms. Advantageously, the C 10 -C 26 alcohols are fatty alcohols, preferably branched when they comprise at least 16 carbon atoms. As examples of fatty alcohols that can be used according to the invention, mention may be made of straight or branched fatty alcohols of synthetic origin, or else natural, for example alcohols derived from vegetable matter (copra, palm kernel, palm ...) or animal (tallow ...). It is also possible to use other long-chain alcohols, for example ether-alcohols or even so-called Guerbet alcohols.
[0014] Finally, it is also possible to use certain longer or shorter cuts of alcohols of natural origin, for example coconut (C12 to C16) or tallow (C16 to C18). It is preferable to use a fatty alcohol comprising from 10 to 24 carbon atoms, and more preferably from 12 to 22 carbon atoms. As particular examples of fatty alcohols which may be used as preferred, there may be mentioned lauryl alcohol, isostearyl alcohol, oleic alcohol, 2-butyloctanol, 2-undecyl pentadecanol, 2-hexyldecyl alcohol, alcohol and the like. isocetyl, octyldodecanol and their mixtures. According to an advantageous embodiment of the invention, the alcohol is chosen from octyldodecanol. And optionally monosters, diesters, triesters, optionally hydroxylated, of a C 2 -C 8 monocarboxylic acid and a C 2 -C 8 alcohol. In particular: monoesters of a C2-C8 carboxylic acid and a C2-C8 alcohol, optionally hydroxylated, diesters of a C2-C8 dicarboxylic acid and of a C2-C8 alcohol optionally hydroxyl; such as diisopropyl adipate, 2-diethylhexyl adipate, dibutyl adipate, or diisostearyl adipate, 2-diethylhexyl succinate, triesters of a C2-C8 triacidecarboxylic acid and a C2 alcohol. -C8, optionally hydroxylated, such as citric acid esters, such as trioctyl citrate, triethyl citrate, acetyl tributyl citrate, tributyl citrate. esters of a C 2 -C 8 olol and of one or more C 2 -C 8 carboxylic acids, such as glycol and monoacid diesters, such as neopentyl glycol diheptanoate, or triesters, glycol and monoacids such as triacetin. Preferably, the first non-volatile hydrocarbon oil is chosen from C 10 -C 26 alcohols, more particularly monoalcohols, and preferably octyldodecanol.
[0015] According to an advantageous embodiment of the invention, the content of first non-volatile hydrocarbon oil (s) represents from 5% to 50% by weight, in particular from 10% to 35% by weight. by weight, relative to the total weight of the composition.
[0016] NON-VOLATILE SILICONE OILS The composition according to the invention may comprise, as additional oil, at least one non-volatile silicone oil chosen from non-volatile silicone oils, in particular phenylated or non-phenylated oils.
[0017] By "silicone oil" is meant an oil containing at least one silicon atom, and in particular containing Si-O groups. Non-phenylated Non-volatile Silicone Oils The term "non-phenyl silicone oil" refers to a silicone oil having no phenyl substituent. Representative examples of such non-volatile, non-phenolic silicone oils which may be mentioned include polydimethylsiloxanes; alkyldimethicones; vinylmethylmethicones; and also silicones modified with aliphatic groups and / or with functional groups such as hydroxyl, thiol and / or amine groups.
[0018] It should be noted that "dimethicone" (INCI name) corresponds to a polydimethylsiloxane (chemical name). The non-phenylated non-volatile silicone oil is preferably chosen from non-volatile dimethicone oils.
[0019] In particular, these oils may be chosen from the following non-volatile oils: polydimethylsiloxanes (PDMSs), PDMSs comprising aliphatic groups, in particular alkyl, or alkoxy groups, which are pendant and / or at the end of the chain silicone; these groups each comprising from 2 to 24 carbon atoms. By way of example, mention may be made of the cetyldimethicone sold under the trade name ABIL WAX 9801 by Evonik Goldschmidt, polyalkylmethylsiloxanes substituted with functional groups such as hydroxyl, thiol and / or amine groups, and polysiloxanes modified with acids. fatty alcohols, fatty alcohols or polyoxyalkylenes, and mixtures thereof. Preferably, these non-volatile, non-phenyl silicone oils are chosen from polydimethylsiloxanes; alkyldimethicones and also PDMSs comprising aliphatic groups, in particular C 2 -C 24 alkyl, and / or functional groups such as hydroxyl, thiol and / or amine groups. The non-phenyl silicone oil may be chosen in particular from silicones of formula (I): ## STR2 ## in which R1, R2, R5 and R6 are, together or separately, an alkyl radical containing 1 to 6 carbon atoms, R3 and R4 are, together or separately, an alkyl radical containing 1 to 6 carbon atoms, a vinyl radical, a amine radical or a hydroxyl radical, X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or an amine radical, n and p are integers chosen so as to have a fluid compound, in particular whose viscosity at 25 ° C is between 9 centistokes (cSt) (9 x 10-6 m2 / s) and 800,000 cSt.
[0020] As non-volatile, non-phenyl silicone oils which can be used according to the invention, mention may be made of those for which: the substituents R 1 to R 6 and X represent a methyl group, and p and n are such that the viscosity is 500,000 cSt, for example the product sold under the name SE30 5 by the company General Electric, the product marketed under the name AK 500000 by Wacker, the product sold under the name Mirasil DM 500 000 by Bluestar, and Dow Corning 200 Fluid 500,000 cSt by Dow Corning; R1 to R6 and X are methyl, and p and n are such that the viscosity is of 60,000 cSt, for example the product sold under the name Dow Corning 200 Fluid 60000 CS by Dow Corning, and the product marketed under the name Wacker Belsil DM 60 000 by the company Wacker, - substituents R 1 to R6 and X represent a methyl group, and p and n are such that the viscosity is 100 cSt or 350 cSt, for example the products marketed under the names Belsil DM100, Dow Corning 200 Fluid 350 CS, respectively by the Dow Corning Company, the substituents R 1 to R 6 represent a methyl group, the X group represents a hydroxyl group, and n and p are such that the viscosity is 700 cSt, for example the product marketed under the name Baysilone Fluid T0 .7 by the company Momentive.
[0021] Nonvolatile Phenyl Silicone Oils The term "phenyl silicone oil" refers to a silicone oil having at least one phenyl substituent. These nonvolatile phenyl silicone oils may be chosen from those which furthermore have at least one dimethicone fragment, or from those which do not have one. The term "dimethicone fragment" denotes a divalent siloxane group whose silicon atom bears two methyl radicals, this group not being at the ends of the molecule. It can be represented by the following formula: - (Si (CH3) 2- 0) -.
[0022] The non-volatile phenyl silicone oil may thus be chosen from: a) phenyl silicone oils with or without a dimethicone fragment corresponding to the following formula (I): RRR R-Si-O II R-Si O-Si RRR 11 Wherein R, monovalent or divalent, represent, independently of one another, methyl, methylene, phenyl or phenylene, provided that at least one R is phenyl. Preferably, in this formula, the phenyl silicone oil comprises at least three phenyl groups, for example at least four, at least five or at least six. b) phenyl silicone oils with or without a dimethicone moiety corresponding to the following formula (2): RRR R-Si-O-Si-O-Si-R RRR (II) in which the R groups are, independently, others, methyl or phenyl, provided that at least one R is phenyl. Preferably, in this formula, the compound of formula (II) comprises at least three phenyl groups, for example at least four or at least five. Mixtures of different silicone phenyl compounds previously described can be used. Examples which may be mentioned include mixtures of triphenyl-, tetraphenyl- or pentaphenyl-organopolysiloxanes. Among the compounds of formula (II), mention may be made more particularly of phenyl silicone oils having no dimethicone fragment corresponding to formula (II) in which at least 4 or at least 5 R radicals represent a phenyl radical, the remaining radicals representing methyl. Such nonvolatile phenyl silicone oils are preferably trimethylpentaphenyltrisiloxane or tetramethyltetraphenyltrisiloxane. They are in particular marketed by Dow Corning under the reference PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: 1,3,5-trimethyl-1,1,3,5,5-pentaphenyltrisiloxane; INCI name: trimethyl -pentaphenyltrisiloxane), or tetramethyltetraphenyltrisiloxane sold under the reference Dow Corning 554 Cosmetic Fluid by Dow Corning can also be used.
[0023] They correspond in particular to the following formulas (III), (III '): Ph Ph Ph Me Ph Me Me-Si-O-Si-O-Si-Me Ph-Si-O-Si-O-Si-Ph 1 1 Ph Me (III) Me Ph Me (III ') in which Me is methyl, Ph is phenyl. c) phenyl silicone oils having at least one dimethicone fragment corresponding to the following formula (IV): ## STR1 ## in which Me represents methyl, y is between 1 and 1000 and X represents -CH2-CH (CH3) (Ph). D) the phenyl silicone oils corresponding to the formula (V) below, and mixtures thereof: ## STR1 ## wherein R 1 is SiO 3 Si-R 7 R 6 m (V) in which: R 1 to R 10, independently of one another, are saturated or unsaturated, linear, cyclic or branched C 1 -C 30 hydrocarbon radicals, - m, n, p and q are, independently of each other, integers between 0 and 900, provided that the sum m + n + q is different from 0. Preferably, the sum m + n + q is between 1 and 100 Advantageously, the sum m + n + p + q is between 1 and 900 and preferably between 1 and 800.
[0024] Preferably, q is equal to 0. More particularly, R 1 to R 10, independently of one another, represent a saturated or unsaturated, preferably saturated, linear or branched C1-C30 hydrocarbon radical, and in particular a hydrocarbon-based radical. , preferably saturated, C 1 -C 20, in particular C 1 -C 18, or a C 6 -C 14 aryl radical and in particular C 10 -C 13, monocyclic or polycyclic, or an aralkyl radical preferably whose alkyl part is in C1-C3. Preferably, R 1 to R 10 may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical. R1 to R10 may in particular be the same, and furthermore may be a methyl radical. According to a first and more particular embodiment of formula (V), mention may be made of: i) phenyl silicone oils with or without at least one dimethicone fragment corresponding to formula (VI) below, and mixtures thereof : ## STR5 ## wherein R 1 to R 6 independently of one another saturated or unsaturated, linear, cyclic or branched C1-C30 hydrocarbon radicals, an aryl radical, preferably a C6-C14 radical, or an aralkyl radical, the alkyl part of which is C1-C3). m, n and p are, independently of each other, integers between 0 and 100, provided that the sum n + m is between 1 and 100. Preferably, R1 to R6, independently of one of the other, represent a hydrocarbon radical, preferably C 1 -C 20 alkyl, in particular C 1 -C 18 alkyl, or a monocyclic (preferably C 6) or polycyclic C 6 -C 14 aryl radical, and in particular C 10 -C 13 aryl, or an aralkyl radical (preferably the aryl part is C 6, the alkyl part is C 1 -C 3). Preferably, R 1 to R 6 may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical. R1 to R6 may in particular be identical, and may furthermore be a methyl radical. Preferably, m = 1 or 2 or 3, and / or n = 0 and / or p = 0 or 1 may be applied, in formula (VI).
[0025] According to a particular embodiment, the non-volatile phenyl silicone oil is chosen from phenyl silicone oils having at least one dimethicone moiety. Preferably, such oils correspond to compounds of formula (VI) in which: A) m = 0 and n and p are independently of one another integers between 1 and 100. Preferably R1 to R6 are methyl radicals. According to this embodiment, the silicone oil is preferably selected from a diphenyldimethicone such as Shin Etsu KF-54 (400 cSt), Shin Etsu KF54HV (5000 cSt), KF-50-300CS from Shin Etsu (300 cSt), cSt), KF-53 from Shin Etsu (175cSt), KF-50-100CS from Shin Etsu (100 cSt).
[0026] B) p is between 1 and 100, the sum n + m is between 1 and 100, and n = 0. These phenyl silicone oils having or not at least one dimethicone fragment corresponding more particularly to the formula (VII) below: Me Me OR 'Me [O-Si-Me Me Me (VII) is phenyl, OR' represents a Me-Si Me P group methyl Me Me Me is Ph m in which and Ph-OSiMe3 and p is 0 or is between 1 and 1000, and m is between 1 and 1000. In particular, m and p are such that the compound (VII) is a non-volatile oil. According to a first embodiment of non-volatile phenyl silicone having at least one dimethicone fragment, p is between 1 and 1000. m is more particularly such that the compound (VII) is a non-volatile oil. It can be used, for example, trimethylsiloxyphenyldimethicone, sold in particular under the reference Belsil PDM 1000 by the company Wacker.
[0027] According to a second embodiment of nonvolatile phenyl silicone having no dimethicone fragment, p is equal to 0. m is between 1 and 1000, and in particular is such that the compound (VII) is a non-volatile oil It may be used, for example, phenyltrimethylsiloxytrisiloxane, sold in particular under the reference Dow Corning 556 Cosmetic Grade Fluid (DC556). Ii) nonvolatile phenyl silicone oils having no dimethicone moiety corresponding to the formula (VIII) below, and mixtures thereof: RR H3C-Si 0 SiO Si-CH 3 ROR Si (CH 3) 3 m (VIII) in which: - R, independently of one another, are saturated or unsaturated, linear, cyclic or branched C1-C30 hydrocarbon radicals, preferably R is a C1-C30 alkyl radical; an aryl radical, preferably C6-C14, or an aralkyl radical whose alkyl part is C1-C3). m and n are, independently of one another, integers between 0 and 100, provided that the sum n + m is between 1 and 100.
[0028] Preferably, R, independently of one another, represent a linear or branched, saturated or saturated, saturated or unsaturated, saturated or unsaturated hydrocarbon-based radical, and in particular a hydrocarbon radical, preferably saturated, C 1 -C 20, in particular C 1 -C 10 and more particularly C 4 -C 10, a C 6 -C 14 aryl radical which is monocyclic or polycyclic and in particular C 10 -C 13, or an aralkyl radical, preferably the aryl part is C 6 and the alkyl part is C 1 C3). Preferably, the R may each represent a methyl, ethyl, propyl, butyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical.
[0029] The radicals R may in particular be identical, and furthermore may be a methyl radical. Preferably, m = 1 or 2 or 3, and / or n = 0 and / or p = 0 or 1 may be applied in formula (VIII). According to a preferred embodiment, n is an integer from 0 to 100 and m is an integer from 1 to 100, provided that the sum n + m is from 1 to 100 in formula (VIII). Preferably R is a methyl radical. According to one embodiment, a phenyl silicone oil of formula (VIII) having a viscosity at 25 ° C of between 5 and 1500 mm 2 / s (i.e., from 5 to 1500 cSt), and preferably having a viscosity of between 5 and 1000 mm 2 / s (i.e. 5 to 1000 cSt) can be used. According to this embodiment, the nonvolatile silicone phenylated oil is preferably chosen from phenyltrimethicones (when n = 0) such as DC556 from Dow Corning (22.5 cSt), or from diphenylsiloxyphenyltrimethicone oil (when m 25 and n are from 1 to 100) such as KF56 A from Shin Etsu, Silbione 70663V30 from Rhône-Poulenc (28 cSt). Values in parentheses represent viscosities at 25 ° C. (e) phenyl silicone oils with or without at least one dimethicone moiety corresponding to the following formula, and mixtures thereof: R1 173 75/1 X - O - Si. O - Si - O - Si - X R2 In which: R1, R2, R5 and R6 are, identical or different, an alkyl radical containing 1 to 6 carbon atoms, R3 and R4 are, identical or different, an alkyl radical containing from 1 to with 6 carbon atoms or an aryl radical (preferably C 6 -C 14), provided that at least one of R 3 and R 4 is a phenyl radical, X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or a vinyl radical, n and p being an integer greater than or equal to 1, chosen so as to give the oil a weight average molecular weight of less than 200 000 g / mol, preferably less than 150 000 g / mole and more preferably less than 100,000 g / mole. F) and a mixture thereof. Advantageously, the content of non-volatile oil (s) silicone (s) represents from 5 to 75% by weight, in particular from 5 to 60% by weight, and preferably from 10 to 50% by weight, relative to the weight of the composition.
[0030] FLUOROUS NON-VOLATILE OILS The composition according to the invention may optionally comprise, as additional oil, at least one non-volatile fluorinated oil. By "fluorinated oil" is meant an oil containing at least one fluorine atom.
[0031] By way of example of fluorinated oils, mention may be made of fluorosilicone oils, fluorinated polyethers and fluorinated silicones, especially as described in document EP-A-847752 and perfluorinated compounds, alone or in mixtures. By perfluorinated compounds is meant according to the invention compounds in which all the hydrogen atoms have been substituted by fluorine atoms.
[0032] According to a preferred embodiment, the fluorinated oil is chosen from perfluorinated oils. As examples of perfluorinated oils, there may be mentioned perfluorodecalines, perfluoperhydrophenanthrenes, perfluorinated ether oils. According to a preferred embodiment, the fluorinated oil is chosen from perfluoperhydrophenanthrenes, and in particular Fiflow® products marketed by Créations Couleurs. In particular, it is possible to use the fluorinated oil whose INCI name is perfluoperhydrophenanthrene, sold under the reference FIFLOW 220 by the company F2 Chemicals, or the perfluoro-polymethylisopropyl ether oil, for example sold under the reference FOMBLIN HC, by Solvay.
[0033] According to one embodiment of the invention, when the composition comprises, the content of non-volatile oil (s) fluorinated (s) represents 1 to 75% by weight, more particularly 1 to 40% by weight. weight, preferably from 1 to 20% by weight, relative to the weight of the composition.
[0034] SECOND NON-VOLATILE HYDROCARBON OILS The composition according to the invention may also comprise, as additional oil, at least a second non-volatile, polar or apolar hydrocarbon-based oil.
[0035] Second non-volatile polar hydrocarbon oils The term "hydrocarbon-based oil" means an oil formed essentially or even consisting of carbon and hydrogen atoms, and possibly oxygen, nitrogen, and non-carbon atoms. silicon atom or fluorine atom.
[0036] It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups. Preferably, the hydrocarbon oil is free, in addition to silicon, of fluorine; heteroatoms such as N, Si and P. The hydrocarbon oil is therefore distinct from a silicone oil and a fluorinated oil.
[0037] In the present case, the nonvolatile hydrocarbon oil comprises at least one oxygen atom. In particular, this nonvolatile hydrocarbon oil, different from the first nonvolatile hydrocarbon oils, is chosen from ester oils having at least 17 carbon atoms, in particular having between 17 and 70 carbon atoms, the oils comprising at least one carbonate function. , their mixtures. As regards the ester oils having at least 18 carbon atoms, mention may be made of mono-, di- or tri-esters. The ester oils may be hydroxylated or not.
[0038] Thus, the nonvolatile ester oil suitable for carrying out the invention may be chosen from: monoesters comprising at least 18 carbon atoms, in particular comprising between 18 and 40 carbon atoms in total, especially monoesters, of formula RiCOOR2 in which R1 represents the residue of a linear or branched or aromatic fatty acid comprising from 4 to 40 carbon atoms, saturated or unsaturated, and R2 represents a hydrocarbon chain, in particular branched, containing from 4 to 40 carbon atoms with the proviso that R1 + R2 is 18, such as, for example, purcellin oil (cetostearyl octanoate), isononyl isononanoate, C12-C15 alcohol benzoate, ethyl palmitate 2 hexyl, octyledodecyl neopentanoate, 2-octyl dodecyl stearate, octyl-2-dodecyl erucate, isostearyl isostearate, octyl-2-dodecyl benzoate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols, myrista isopropyl ether, isopropyl palmitate, butyl stearate, hexyl laurate, 2-ethylhexyl palmitate, 2-hexyl-decyl laurate, 2-octyl decyl palmitate, 2-Octyldodecyl myristate.
[0039] Preferably, these are the esters of formula R 1 COROR 2 in which R 1 represents the residue of a linear or branched fatty acid containing from 4 to 40 carbon atoms and R 2 represents a hydrocarbon chain, in particular a branched hydrocarbon chain containing from 4 to 40 atoms. of carbon, R1 and R2 being such that R1 + R2 is 18.
[0040] Still more particularly, the ester comprises between 18 and 40 carbon atoms in total. As preferred monoesters, there may be mentioned isononyl isononanoate, oleyl erucate and / or octy1-2-docecyl neopentanoate; Fatty acid monoesters comprising at least 18 carbon atoms, and in particular having 18 to 22 carbon atoms, and diols. In particular, it may be esters of lanolic acid, oleic acid, lauric acid, stearic acid, and diols, such as propylene glycol monoisostearate. Diesters comprising at least 17 carbon atoms, especially comprising between 17 and 60 carbon atoms in total, in particular between 17 and 50 carbon atoms in total, linear or branched, saturated, unsaturated or aromatic, optionally hydroxylated. It is thus possible to use more particularly diesters of dicarboxylic acid, optionally hydroxylated, and saturated or unsaturated monoalcohols, such as diisostearyl malate. It is also possible to use glycol diesters, especially C 2 -C 5, glycerol or diglycerol and linear or branched, saturated, unsaturated or aromatic carboxylic monoacids, such as neopentyl glycol dicaprate or propylene glycol dioctanoate. propylene glycol dibenzoate, diethylene glycol diisononanoate, or polyglyceryl-2-diisostearate (especially such as the compound sold under the commercial reference Dermol DGDIS by the company Alzo). Hydroxylated monoesters and diesters comprising at least 18 carbon atoms, preferably having a carbon number ranging from 18 to 70, such as polyglyceryl-3-diisostearate, isostearyl lactate, octyl hydroxystearate, hydroxystearate, and the like. octyldodecyl, diisostearyl malate, glycerine stearate. The triesters comprising at least 35 carbon atoms, in particular comprising between 35 and 70 carbon atoms in total, in particular such as the triacid carboxylic triesters, such as triisostearyl citrate, or tridecyl trimellitate, or the glycol triesters. and mono carboxylic acids such as polyglycerol triisostearate. Tetraesters comprising at least 35 carbon atoms, in particular having a total number of carbon ranging from 35 to 70, such as the tetraesters of penthaerythritol or of polyglycerol and of a monocarboxylic acid, for example such as pentaerythrityl tetrapelargonate, tetraisostearate pentaerythrityl, pentaerythrityl tetraisonanoate, glyceryl tri-2-tetradecanoate, polyglyceryl-2 tetraisostearate or pentaerythrityl tetra decyl-2 tetradecanoate. The polyesters obtained by condensation of dimer and / or trimer of unsaturated fatty acid and of diol, such as those described in patent application FR 0 853 634, such as in particular dilinoleic acid and , 4-butanediol. Mention may in particular be made of the polymer marketed by Biosynthis under the name Viscoplast 14436H (INCI name: dilinoleic acid / butanediol copolymer), or the copolymers of polyols and diacid dimers, and their esters, such as Hailucent ISDA. The esters and polyesters of diol dimer and of mono- or dicarboxylic acid, such as esters of diol dimer and of fatty acid and esters of dimer diols and dimer of dicarboxylic acid, in particular obtainable from dimer a dicarboxylic acid dimer derived in particular from the dimerization of an unsaturated fatty acid, especially of C 8 to C 34, in particular C 12 to C 22, in particular C 16 to C 20, and more particularly to C 10, such as dilinoleic diacid esters; and dilinoleic diol dimers, for example such as those marketed by the company NIPPON FINE CHEMICAL under the trade name LUSPLAN DD-DA5® and DD-DA7®. Polyesters resulting from the esterification of at least one triglyceride of carboxylic acid (s) hydroxylated with an aliphatic monocarboxylic acid and with an optionally unsaturated aliphatic dicarboxylic acid, such as castor oil, succinic acid and isostearic acid sold under the reference Zénigloss by Zenitech. * Vegetable hydrocarbon oils such as triglycerides of fatty acids (liquid at room temperature), especially of fatty acids having from 7 to 40 carbon atoms, such as triglycerides of heptanoic or octanoic acids or jojoba oil in particular, there may be mentioned saturated triglycerides such as caprylic / capric triglyceride and mixtures thereof, for example such as that marketed under the reference Cognis Myritol 318, glyceryl triheptanoate, glycerol trioctanoate, acid triglycerides. C18-36 such as those marketed under the reference DUB TGI 24 25 marketed by Stéarineries Dubois), and unsaturated triglycerides such as castor oil, olive oil, ximenia oil, pracaxi. Sucrose esters, preferably selected from hydrocarbon esters of sucrose and of C2-C6 carboxylic acid, in particular those chosen from mixtures of acetic acid and isobutyric acid esters with sucrose, of preferably sucrose di-acetate-hexa- (2-methyl-propanoate), in particular the compound whose INCI name is Sucrose Acetate Isobutyrate (in particular sold under the reference Sustane Saib Kosher Food Grade by the company Eastman Chemicals) and the compounds of name INCI Sucrose Polyosoyate sold under the reference Crodaderm S by Croda, Sucrose Polybénénate sold under the reference Crodaderm 35 B by Croda, Sucrose Polycottonseedate sold under the reference Crodaderm C by Croda; and their mixtures. With regard to the oils comprising at least one carbonate function, di-alkyl carbonates may be particularly mentioned, the 2 alkyl chains being identical or different, such as caprylyl carbonate sold under the name Cetiol CC®. by Cognis, diethylhexyl carbonate for example sold under the reference Tegosoft DEC by Evonik-Goldschmidt Personal Care, and mixtures thereof.
[0041] According to a preferred embodiment, the at least one polar non-volatile hydrocarbon-based oil is chosen from monoesters comprising at least 18 carbon atoms, from the diesters comprising at least 17 carbon atoms, alone or in mixtures. If the composition contains, the content of second (s) oil (s) nonvolatile (s) polar hydrocarbon (s) represents 1 to 35% by weight, preferably 5 to 20% by weight, relative to the weight of the composition. Second non-volatile apolar hydrocarbon oils The composition according to the invention may also comprise at least one second apolar nonvolatile hydrocarbon oil. These oils can be of vegetable, mineral or synthetic origin. For the purposes of the present invention, the term "apolar oil" means an oil whose solubility parameter at 25 ° C., 6a, is equal to 0 (J / cm 3) 1/4. The definition and calculation of the solubility parameters in the HANSEN three-dimensional solubility space are described in the article by C. M. Hansen: "The three dimensional solubility parameters" J. Paint Technol. 39, 105 (1967). According to this Hansen space: - SD characterizes the dispersion forces of LONDON resulting from the formation of dipoles induced during molecular shocks; Δp characterizes the DEBYE interaction forces between permanent dipoles as well as the KEESOM interaction forces between induced dipoles and permanent dipoles; hh characterizes the specific interaction forces (hydrogen bond, acid / base, donor / acceptor, etc.) type; and - 15a is determined by the equation: 15a = (15 p2hl / 2 The parameters δp, δh, 15D and δa are expressed in (J / cm3) 1/4. "Hydrocarbon oil" means an oil formed essentially or even consisting of carbon and hydrogen atoms, and optionally oxygen, nitrogen, and not containing silicon or fluorine atom.It may contain alcohol, ester groups , ether, carboxylic acid, amine and / or amide.
[0042] Preferably, the non-volatile apolar hydrocarbon oil may be chosen from linear or branched hydrocarbons of mineral or synthetic origin, such as: paraffin oil or its derivatives, squalane, isoeicosane , Naphthalene oil, polybutenes, hydrogenated or not, such as, for example, INDOPOL H-100 (of molar mass or MW = 965 g / mol), INDOPOL H-300 (MW = 1340 g / mol), INDOPOL H-1500 (MW = 2160 g / mol) marketed or manufactured by AMOCO, 5-polyisobutenes, hydrogenated polyisobutenes such as for example Parleam® sold by the company Nippon Oil Fats, PANALANE H-300 E marketed or manufactured by AMOCO (MW = 1340 g / mol), VISEAL 20000 marketed or manufactured by SYNTEAL (MW = 6000 g / mol), REWOPAL PIB 1000 marketed or manufactured by WITCO company (MW = 1000 g / mol), or the PARLEAM LITE marketed by NOF Corporat ion, decene / butene copolymers, polybutene / polyisobutene copolymers, in particular Indopol L-14, polydecenes and hydrogenated polydecenes, such as, for example: PURESYN 10 (MW = 723 g / mol), PURESYN 150 ( MW = 9200 g / mol) marketed or manufactured by MOBIL CHEMICALS, or PURESYN 6 marketed by EXXONMOBIL CHEMICAL), and mixtures thereof. Advantageously, the content of the second non-volatile hydrocarbon oil (s) is (s) from 1 to 75% by weight, in particular from 1 to 60% by weight, more particularly from 1 to 35% by weight, relative to the total weight of the composition. According to a first particular embodiment of the present invention, the composition according to the invention comprises at least one first nonvolatile hydrocarbon oil and at least one additional oil chosen from silicone oils, fluorinated oils and second non-hydrocarbon oils. volatile, polar or apolar, as well as their mixtures. Preferably, the first non-volatile hydrocarbon oil or oils are chosen from monoalcohols.
[0043] Preferably, the composition also comprises an additional oil chosen from nonvolatile silicone oils, phenylated or otherwise, alone or in mixtures. More particularly, said one or more silicone oils are chosen from non-volatile, more particularly phenylated, silicone oils. Preferably, the or silicone phenylated oils are chosen from the 35 phenyltrimethicones, phenyldimethicones, phényltriméthylsiloxy diphenylsiloxanes, tetramethyl tetraphenyl trisiloxane, phényltriméthylsiloxytrisiloxane the diphénylsiloxyphényl trimethicones, diphenyl dimethicones, diphenylmethyldiphenyltrisiloxanes, the triméthylsiloxyphényldiméthicones, the triphenyl trimethicones, trimethyl pentaphenyl trisiloxanes, and mixtures thereof.
[0044] According to a preferred embodiment, the phenyl silicone oil may be chosen from trimethylsiloxyphenyldimethicones, phenyltrimethicones, trimethylpentaphenyltrisiloxanes and diphenylsiloxyphenyl trimethicones, and mixtures thereof. According to this variant, the composition may also comprise at least a second polar or nonpolar nonvolatile hydrocarbon oil, at least one fluorinated nonvolatile oil, and preferably at least one second polar or nonpolar nonvolatile hydrocarbon oil. According to this particular variant, the content of second (s) hydrocarbon oil (s) nonvolatile (s) polar (s) or apolar (s) represents 1 to 35% by weight, relative to the weight of the composition . According to a second particular embodiment of the present invention, the additional oil or oils are chosen from the second non-volatile hydrocarbon oils, which are polar and different from the first or non-polar oils.
[0045] Preferably, the second hydrocarbon-based oils are chosen from apolar oils, in particular hydrogenated or non-hydrogenated poly (iso) butene, hydrogenated or non-hydrogenated polydecenes, and mixtures thereof. According to this variant, the composition may also comprise at least one non-volatile fluorinated oil, preferably at a content of between 1 and 20% by weight, relative to the weight of the composition. According to a particularly preferred embodiment, the composition according to the invention comprises a total content of non-volatile oils (first (s) and second (s) non-volatile hydrocarbons, silicone oils, fluorinated oils) of between 20 and 80% by weight. weight, preferably between 40 and 75% by weight, relative to the total weight of the composition. VOLATILE OPTIONAL OILS The composition according to the invention may further comprise at least one optional volatile oil. Preferably, said volatile oil is chosen from volatile hydrocarbon oils, volatile silicone oils and / or volatile fluorinated oils. The optional volatile oil may especially be a silicone oil, a hydrocarbon oil, preferably apolar, or a fluorinated oil.
[0046] According to a first embodiment, the optional volatile oil is a silicone oil and can in particular be chosen from silicone oils having a flash point ranging from 40 ° C. to 102 ° C., preferably having a flash point greater than 55 ° C. C and less than or equal to 95 ° C, and preferably ranging from 65 ° C to 95 ° C.
[0047] As optional volatile silicone oils that can be used in the invention, mention may be made of linear or cyclic silicones having a viscosity at ambient temperature of less than 8 centistokes (cSt) (8 × 10 -6 m 2 / s), and having, in particular, from 2 to 10 silicon atoms, and in particular from 2 to 7 silicon atoms, these silicones optionally containing alkyl or alkoxy groups having from 1 to 10 carbon atoms. As the volatile silicone oil that may be used in the invention, mention may be made, in particular, of dimethicones of viscosity 5 and 6 cSt, octamethyl cyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, heptamethyloctyltrisiloxane, hexamethyl disiloxane, octamethyl trisiloxane, decamethyl tetrasiloxane, dodecamethyl pentasiloxane, and mixtures thereof. According to a second embodiment, the optional volatile oil is a fluorinated oil, such as nonafluoromethoxybutane or perfluoromethylcyclopentane, and mixtures thereof. According to a third embodiment, the optional volatile oil is a hydrocarbon oil, preferably apolar. The optional apolar volatile hydrocarbon oil may have a flash point ranging from 40 ° C to 102 ° C, preferably from 40 ° C to 55 ° C, and preferably from 40 ° C to 50 ° C. The optional volatile hydrocarbon oil may in particular be chosen from volatile hydrocarbon oils having from 8 to 16 carbon atoms and mixtures thereof, and in particular: C8-C16 branched alkanes such as isoalkanes (also known as isoparaffins) C8-C16, isododecane, isodecane, isohexadecane, and for example the oils sold under the trade names Isopars or permetyls, -the linear alkanes, for example such as n-dodecane (C12 ) and n-tetradecane (C14) sold by Sasol respectively under the references PARAFOL 12-97 and PARAFOL 14-97, as well as their mixtures, the undecane-tridecane mixture (cetol UT), the mixtures of n-undecane (C11) and n-tridecane (C13) obtained in Examples 1 and 2 of Application WO2008 / 155059 from Cognis and mixtures thereof.
[0048] According to one particular embodiment, the optional volatile oil (s) may be present in a content ranging from 0.1 to 30% by weight, in particular from 0.5 to 20% by weight, relative to the total weight of said composition. Advantageously, the composition contains less than 10% by weight of monoalcohols having 1 to 5 carbon atoms, preferably less than 5% by weight. According to a particular embodiment, the composition may be free of monoalcohols having from 1 to 5 carbon atoms. According to a preferred embodiment, the composition is free of optional volatile oil.
[0049] HYDROCARBON RESIN The composition according to the invention comprises at least one resin with a number average molecular weight of less than or equal to 10,000 g / mol. Advantageously, the softening point of the resin varies from 70 to 130 ° C., more particularly from 80 to 120 ° C., and preferably from 90 to 110 ° C. (ASTM E 28 standard). Advantageously, this number-average molecular weight from 250 g / mol to 10,000 g / mol, preferably from 250 g / mol to 5,000 g / mol, more preferably from 250 g / mol to 2,000 g / mol, or even from 250 g / mol to 1,000 g / mol. The number average molecular weights (Mn) were determined by gel permeation liquid chromatography (THF solvent, calibration curve established with linear polystyrene standards, refractometric detector). As aliphatic hydrocarbon resin, mention may be made in particular of: hydrogenated indene / methyl styrene / styrene copolymers for example sold under the name REGALITE by the company Eastman Chemical, in particular REGALITE R1090, REGALITE R1100, REGALITE S1100, and REGALITE S5100, or under the name ARKON P-90, ARKON P-100, and ARKON P-115, by Arakawa; aliphatic pentanediene resins such as, in particular, those resulting from the polymerization predominantly of 1,3-pentanediene (trans or cis-piperylene) monomers and of a minority monomer chosen from isoprene, butene and 2-methyl-2-butene; pentene, 1,4-pentanediene and mixtures thereof. These resins may have a molecular weight ranging from 1000 to 2500 g / mol. Such 1,3-pentanediene resins are sold, for example, under the references PICCOTAC 95 by the company Eastman Chemical, ESCOREZ 1102, ESCOREZ 1304, ESCOREZ 1310LC, ESCOREZ 1315 by Exxon Chemicals, WINGTACK 95 by Cray Valley; diene resins of dimers of cyclopentanediene, for example such as those resulting from the polymerization of dicyclopentanediene, methyldicyclopentanediene, the other dimers of pentanediene, and mixtures thereof. These resins generally have a molecular weight ranging from 500 to 800 g / mol, such as for example those sold under the reference ESCOREZ 5380, ESCOREZ 5300, ESCORE 5400, ESCORE 5415, ESCORE 5490, by the company Exxon Mobil Chem., And SUKOREZ SU-90, SUKOREZ SU-100, SUKOREZ SU-110, SUKOREZ SU-100S, SUKOREZ SU-200, SUKOREZ SU-210, SUKOREZ SU-490, SUKOREZ SU-400, by Kolon; The hydrogenated resins resulting from the polymerization of pentanediene, such as those sold under the name EASTOTAC H-100E, EASTOTAC H-115E, EASTOTAC C-100L, EASTOTAC C-115L, EASTOTAC H-100L, EASTOTAC H-115L, EASTOTAC C-100R, EASTOTAC C-115R, EASTOTAC H-100R, EASTOTAC H-115R, EASTOTAC C-100W, EASTOTAC C-115W, EASTOTAC H-100W, EASTOTAC 40 H-115W, by Eastman Chemical Co.; And their mixtures. The resin is, for example, the hydrogenated indene / methylstyrene / styrene copolymer sold in particular under the name REGALITE R1110 by the company Eastman Chemical, or the aliphatic resin of 1,3-pentanediene sold under the name PICCOTAC 1095 by the company Eastman Chemical. Preferably, the resins according to the invention are chosen from aliphatic hydrocarbon resins, in particular the hydrogenated indene / methylstyrene / styrene copolymer. Preferably, the resin content according to the invention is from 2% to 20% by weight, more particularly from 2% to 18% by weight, preferably from 3% to 16% by weight relative to the total weight of the composition. . HYDROPHILIC GELIFIFIERS The composition according to the invention preferably comprises at least one hydrophilic gelling agent chosen from polymers of natural origin, optionally modified. The term "hydrophilic gelling agent" or "gelling polymer of the aqueous phase", within the meaning of the present application, a polymer capable of gelling the aqueous phase of the compositions according to the invention. The gelling polymer that may be used according to the invention may especially be characterized by its capacity to form in water, beyond a certain concentration C *, a gel characterized by oscillatory rheology (.lambda. = 1 Hz) by a threshold of flow 2c at least equal to 10 Pa. This concentration C * can vary widely depending on the nature of the gelling polymer considered.
[0050] In particular, said polymer is chosen from: galactomannans and their derivatives, such as carob gum, Fennugrec gum, cassia gum, guar gums and their derivatives. As regards the guar gum derivatives, more particularly is meant non-ionic guar gums modified with C 1 -C 6 hydroxyalkyl groups.
[0051] Among the hydroxyalkyl groups, there may be mentioned, by way of example, hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups. These guar gums are well known in the state of the art and may, for example, be prepared by reacting corresponding alkene oxides, such as, for example, propylene oxides, with guar gum so as to obtain guar gum modified with hydroxypropyl groups. The level of hydroxyalkylation, which corresponds to the number of alkylene oxide molecules consumed by the number of free hydroxyl functions present on the guar gum, preferably varies from 0.4 to 1.2. Such nonionic guar gums optionally modified with hydroxyalkyl groups are for example sold under the trade names JAGUAR HP8, JAGUAR HP60 and JAGUAR HP120, JAGUAR DC 293 and JAGUAR HP 105 by the company RHONE POULENC (MEYHALL) or under the name GALACTASOL 4H4FD2 by AQUALON. It is also possible to use ionic alkylguar derivatives, and particularly hydroxypropylguar, modified with sodium methylcarboxylate groups (for example the product marketed under the reference Jaguar XC97-1 by Rhodia), hydroxypropyltrimethyl guar chloride. ammonium, and mixtures thereof. biopolysaccharide gums of microbial origin, such as scleroglucan or xanthan gums.
[0052] The xanthan gums are sold in particular under the names Keltrol, Keltrol T, Keltrol TF, Keltrol BT, Keltrol RD, Keltrol CG by Nutrasweet Kelco, or under the names Rhodicare S, Rhodicare H by Rhodia Chimie. gums derived from vegetable exudates such as the gums Arabica, Ghatti, Karaya, Tragacanth, Carrageenan, Agar and Carob; Pectins, alginates, starches; - their mixtures. Preferably, the composition comprises at least one hydrophilic gelling agent chosen from guar gums and their derivatives, preferably chosen from guar gum, hydroxypropyl guar, hydroxypropylguar modified with sodium methylcarboxylate groups, guar chloride and the like. hydroxypropyl tri-methyl ammonium, xanthan gum, and mixtures thereof; preferably hydroxypropyl guar. According to a particularly advantageous embodiment of the invention, the hydrophilic gelling agent content represents from 0.1 to 20% by weight, preferably from 0.1 to 10% by weight, and more particularly from 0.1 to 5% by weight. % by weight, based on the weight of the composition. The composition may also comprise at least one C2-C8 polyol, preferably C3-C6, saturated or unsaturated, linear or branched, comprising from 2 to 6 hydroxyl groups. The polyol is preferably chosen from glycerine, propylene glycol, 1,3-butylene glycol, dipropylene glycol and diglycerine, and mixtures thereof. Preferably, the polyol content represents from 0.1 to 20% by weight. preferably from 1 to 10% by weight, and more preferably from 2 to 6% by weight, based on the weight of the composition. SURFACTANTS The composition according to the invention may contain one or more surface-active agents, present for example in a content ranging from 0.1% to 20% by weight, or even from 0.5% to 15% by weight, preferably from 1% to 10% by weight, relative to the total weight of the composition. A surfactant preferably selected for use in obtaining a stable emulsion, more particularly an oil-in-water emulsion, is preferably used.
[0053] These surfactants may be selected from nonionic, anionic, cationic, amphoteric surfactants and mixtures thereof, preferably nonionic, anionic surfactants. Reference can be made to "Encyclopedia of Chemical Technology, KIRKOTHMER", Vol. 22, p. 333-432, 3rd edition, 1979, Wiley, for the definition of the properties and emulsifying functions of surfactants, in particular p. 347-377 of this reference, for anionic, amphoteric and nonionic surfactants. According to a first embodiment, the composition comprises at least one hydrocarbon surfactant.
[0054] Nonionic surfactants The nonionic surfactants may be chosen in particular from polyethylene oxide alkyl and polyalkyl esters, oxyalkylenated alcohols, poly (ethylene oxide) alkyl and polyalkyl ethers, polyoxyethylenated or unsaturated alkyl and polyalkyl esters of polyoxyethylenated or unsaturated alkyl and polyalkyl ethers, alkyl and polyalkyl glycosides or polyglycosides, in particular alkyl and polyalkyl glucosides or polyglucosides, sucrose alkyl and polyalkyl esters, polyoxyethylenated or unsubstituted glycerol alkyl and polyalkyl esters, polyoxyethylenated or non-polyoxyethylated alkyl- and polyalkyl ether ethers and mixtures thereof. (1) Poly (ethylene oxide) alkyl and polyalkyl esters are preferably those having a number of ethylene oxide units (OE) of from 2 to 200. For example, stearate 40 OE, stearate 50 OE, stearate 100 OE, laurate 20E, laurate 40 OE, distearate 150 OE. (2) Poly (ethylene oxide) alkyl and polyalkyl ethers are preferably those having a number of ethylene oxide units (OE) of from 2 to 200. For example, cetyl ether 23 OE, oleyl ether 50 OE, phytosterol 30E. (3) Oxylalkylenated alcohols, in particular oxyethylenated and / or oxypropylenated alcohols, are preferably used, fatty alcohols comprising in particular at least 8 carbon atoms, and which may comprise from 1 to 150 oxyethylene and / or oxypropylene units, in particular having from 20 to 20 carbon atoms. 100 oxyethylene units; especially fatty alcohols, in particular C 8 -C 24, and preferably C 12 -C 18, ethoxylated such as ethoxylated stearyl alcohol with 10 oxyethylene units (CTFA name "Steareth-10"), stearyl alcohol ethoxylated with 20 oxyethylene units (CTFA name "Steareth-20") such as BRU 78 marketed by UNIQEMA, stearyl alcohol ethoxylated with 100 oxyethylene units (CTFA name "Steareth-100"), ethoxylated ethoxylated alcohol with 30 units 40 oxyethylene (CTFA name "Ceteareth-30") and the mixture of C12-C15 fatty alcohols containing 7 oxyethylene units (CTFA name "C1245 Pareth-7"), such as that sold under the name NEODOL 25-7® by Shell Chemicals ; ethylene behenyl alcohol containing 100 oxyethylene units (CTFA name "beheneth-100") or in particular the oxyalkylenated (oxyethylenated and / or oxypropylenated) alcohols having from 1 to 15 oxyethylene and / or oxypropylene units, in particular the fatty alcohols in C8-C24, and preferably C12-C18, ethoxylated such as ethoxylated stearyl alcohol with 2 oxyethylene units (CTFA name "Steareth-2") such as BRIJ 72 sold by the company UNIQEMA; ethoxylated stearyl alcohol containing 20 oxyethylene units (CTFA name "Steareth20"), such as BRIJ 78 sold by the company UNIQEMA, 4) Polyoxyethylenated or non-polyoxyethylenated alkyl and polyalkyl esters are preferably used. number of units of ethylene oxide (OE) ranging from 0 to 100. For example, sorbitan laurate 4 or 20 OE may be mentioned, in particular polysorbate 20 (or polyoxyethylene (20) sorbitan monolaurate), such as the product Tween 20 sold by Uniqema, sorbitan palmitate 20 0E, sorbitan stearate 20 OE, sorbitan oleate 20 OE or Cremophor (RH 40, RH 60 ...) from BASF. As non-polyoxyethylenated alkyl and polyalkyl esters of sorbitan, a mixture of sorbitan stearate and sucrose cocoate, preferably that marketed under the reference Arlacel 2121U from Croda, is preferably used. (5) Polyoxyethylenated or unsubstituted polyoxyethylenated alkyl and polyalkyl ethers are preferably used with those having a number of ethylene oxide units (OE) of from 0 to 100. As alkyl and polyalkylenes, Preferably, those containing an alkyl group having from 6 to 30 carbon atoms and preferably from 6 to 18 or even from 8 to 16 carbon atoms, and containing a glucoside group preferably comprising from 1 to 5 carbon atoms, are preferably used. at 5, especially 1, 2 to 3 units of glucoside. The alkylpolyglucosides may be chosen for example from decylglucoside (AlkylC9 / Cii-polyglucoside (1.4)) such as the product sold under the name Mydol 10® by the company Kao Chemicals or the product marketed under the name Plantacare 2000 UP® by Henkel and the product marketed under the name ORAMIX NS 10® by the company SEPPIC; caprylyl / capryl glucoside, such as the product marketed under the name Plantacare KE 3711® by the company Cognis or ORAMIX CG 110® by the company SEPPIC; laurylglucoside, such as the product marketed under the name Plantacare 1200 UP® by Henkel or Plantaren 1200 N® by Henkel; cocoglucoside, such as the product marketed under the name Plantacare 818 UP® by Henkel; caprylylglucoside, such as the product marketed under the name Plantacare 810 UP® by Cognis; and their mixtures. More generally, alkylpolyglycoside surfactants are defined more specifically later. 7) Examples of sucrose alkyl and polyalkyl esters are Crodesta F150, sucrose monolaurate sold under the name Crodesta SL 40, products sold by Ryoto Sugar Ester, for example sucrose palmitate. sold under the reference Ryoto Sugar Ester P1670, Ryoto 5 Sugar Ester LWA 1695, Ryoto Sugar Ester 01570. 8) As alkyl and polyalkyl esters of glycerol, polyoxyethylenated or otherwise, those having a number of units are preferably used. ethylene oxide (OE) ranging from 0 to 100 and a number of glycerol units ranging from 1 to 30. For example, hexaglyceryl monolaurate and PEG-30 glyceryl stearate, glyceryl stearate. 9) As polyoxyethylenated or non-polyoxyethylenated alkyl and polyalkyl ether ethers, those having a number of ethylene oxide units (OE) ranging from 0 to 100 and a number of glycerol units ranging from 1 are preferably used. As an example, mention may be made of Nikkol Batyl Alcohol 100, Nikkol Chemyl Alcohol 100.
[0055] Anionic Surfactants The anionic surfactants may be chosen from alkyl (ether) sulphates, carboxylates, amino acid derivatives, sulphonates, isethionates, taurates, sulphosuccinates, alkyl sulphoacetates, phosphates and alkyl phosphates, polypeptides, metal salts of C10-C30 fatty acids, in particular C12-C20 fatty acids, in particular metal stearates and mixtures thereof. 1) Alkali metal alkyl sulfates and alkyl ether sulfates, for example having at least 12 carbon atoms, more particularly 12 to 16 carbon atoms, and optionally comprising from 1 to 20 oxyethylenated units, more particularly from 1 to 10 units oxyethylenated. Mention may be made, for example, of sodium lauryl sulphate, sodium lauryl ether sulphate (C 12-14 70-30) (2.2 OE) sold under the names SIPON AOS225 or TEXAPON N702 by the company Henkel, lauryl ether sulphate and the like. ammonium (C12-14 70-30) (30E) marketed under the name SIPON LEA 370 by the company Henkel, the alkyl (C12-C14) ether (90 E) ammonium sulphate sold under the name RHODAPEX AB / 20 by Rhodia Chimie, and the mixture of lauryl and oleyl ether sulfate of sodium and magnesium sold under the name EMPICOL BSD 52 by Albright & Wilson. 2) As carboxylates, there may be mentioned for example the (for example alkaline) salts of N-acylamino acids, glycolcarboxylates, amido ether carboxylates (AEC) and polyoxyethylenated carboxylic acid salts.
[0056] The glycol carboxylate surfactant may be selected from alkyl carboxylic or 2- (2-hydroxyalkyloxy acetate), their salts and mixtures thereof. These alkyl glycol carboxylic acids comprise a linear or branched alkyl chain, saturated or unsaturated, aliphatic and / or aromatic, having from 8 to 18 carbon atoms. These carboxylic acids can be neutralized with mineral bases such as potassium hydroxide or sodium hydroxide.
[0057] As surfactants of the carboxylic glycol type, mention may be made, for example, of sodium lauryl glycol carboxylate or 2- (2-hydroxyalkyloxy sodium acetate), such as the product sold under the name Beaulight Shaa ° by the company Sanyo, Beaulight LCA. 25N® or the corresponding acid form Beaulight Shaa (Acid form) ().
[0058] As the amido ether carboxylate (AEC), there may be mentioned, for example, sodium lauryl amido ether carboxylate (30E), sold under the name Akypo Foam 30 ° by the company Kao Chemicals. As the polyoxyethylenated carboxylic acid salt, mention may be made, for example, of sodium lauryl ether carboxylate (C12-14-16 65/25/10) oxyethylenated (60E) sold under the name AKYPO SOFT 45 NV® by the company Kao Chemicals, the polyoxyethylenated and carboxymethylated olive oil fatty acids sold under the name OLIVEM 400 ° by the company BIOLOGIA E TECNOLOGIA, the oxyethylenated tri-decyl ether carboxylate (60E) marketed under the trademark NIKKOL ECTD-6NEX ® by the company Nikkol. 3) As amino acid derivatives, there may be mentioned in particular the alkaline salts of amino acids, such as: sarcosinates, such as sodium lauroyl sarcosinate sold under the name SARKOSYL NL 97® by the company Ciba or sold under the name ORAMIX 30 ° by the company Seppic, sodium myristoyl sarcosinate sold under the name NIKKOL SARCOSINATE MN® by the company Nikkol, the sodium palmitoyl sarcosinate sold under the name NIKKOL SARCOSINATE PN ° by the company Nikkol. alaninates, such as the sodium N-lauroyl-N-methyl amidopropionate sold under the name Sodium Nikkol Alkanate LN 30 ° by the company Nikkol, or sold under the name Alanone Ale® by the company Kawaken, N-lauroyl N- methyl alanine triethanolamine sold under the name ALANONE ALTA ° by the company Kawaken. glutamates, such as the triethanolamine mono-cocoyl glutamate sold under the name ACYLGLUTAMATE CT-12® by the company Ajinomoto, the triethanolamine lauroylglutamate sold under the name ACYLGLUTAMATE LT-12® by the company Ajinomoto. aspartates, such as the mixture of N-lauroyl aspartate triethanolamine / Nmyristoyl aspartate triethanolamine marketed under the name ASPARACK ° by the company Mitsubishi. Glycine derivatives (glycinates), such as sodium N-cocoyl glycinate sold under the names Amilite GCS-12® and Amilite GCK 12 by the company Ajinomoto. citrates, such as the citric monoester of oxyethylenated coconut alcohols (9 moles), sold under the name WITCONOL EC 1129 by the company Goldschmidt, the citric acid monoester of glyceryl stearate. Galacturonates such as sodium dodecyl D-galactoside uronate marketed by the company Soliance. 4) As sulphonates, mention may be made, for example, of alpha-olefin sulphonates, such as sodium alpha-olefin sulphonate (C14-16) sold under the name BIO-TERGE AS-40® by the company Stepan, marketed under the names WITCONATE AOS PROTEGE® and SULFRAMINE AOS PH 12® by the company Witco or sold under the name BIO-TERGE AS-40 CG® by Stepan, the secondary sodium olefin sulfonate marketed under the name HOSTAPUR SAS 30® by the company Clariant; 5) As isethionates, there may be mentioned acylisethionates such as sodium cocoylisethionate, such as the product sold under the name JORDAPON CI P® by the company Jordan. 6) As taurates, mention may be made of the sodium salt of palm kernel oil methyltaurate marketed under the name HOSTAPON CT PATE® by the company Clariant; N-acyl N-methyltaurates, such as sodium N-cocoyl N-methyltaurate sold under the name HOSTAPON LT-SF® by the company Clariant or sold under the name NIKKOL CMT-30-T® by the company Nikkol, palmitoyl methyltaurate sodium sold under the name NIKKOL PMT® by the company Nikkol. 7) As sulfosuccinates, mention may be made, for example, of oxyethylenated (30E) lauryl alcohol (C12 / C14 70/30) monosulphysuccinate sold under the names SETACIN 103 SPECIAL®, REWOPOL SB-FA 30 K 4® by Witco, the di-sodium salt of a hemi-sulfosuccinate of C12-C14 alcohols, sold under the name SETACIN F SPECIAL PASTE® by the company Zschimmer Schwarz, the oxyethylenated (20E) di-sodium dioledosulphosuccinate sold under the name STANDAPOL SH 135® by Henkel, the oxyethylenated lauric amide mono-sulfosuccinate (50E) marketed under the name LEBON A5000® by Sanyo, the di-sodium salt of oxyethylenated lauryl citrate monosulfinate ( 10 0E) marketed under the name REWOPOL SB CS 50® by Witco, the ricinoleic mono-ethanolamide mono-sulfosuccinate sold under the name REWODERM S 1333® by the company Witco. It is also possible to use polydimethylsiloxane sulphosuccinates such as the disodium PEG-12 dimethicone sulphosuccinate marketed under the name MACKANATE-DC30 by Mac Intyre. 8) As alkyl sulphoacetate, mention may be made, for example, of the mixture of sodium lauryl sulphoacetate and di-sodium lauryl ether sulphosuccinate, sold under the name Stepan-Lactin LSB by the company Stepan. 9) Phosphates and alkylphosphates include, for example, monoalkyl phosphates and dialkyl phosphates, such as lauryl monophosphate sold under the name MAP 20® by the company Kao Chemicals, and the potassium salt thereof. dodecylphosphoric acid, a mixture of mono- and di-ester (majority diester) sold under the name CRAFOL AP-31® by the company Cognis, the mixture of monoester and octylphosphoric acid di-ester, marketed under the name CRAFOL AP-20® by the company Cognis, the mixture of ethoxylated 2-butyloctanol phthalic acid monoester and diester (7 moles of EO), sold under the name ISOFOL 12 7 EO-PHOSPHATE ESTER® by the company Condea , the monoalkyl (C12-C13) phosphate or triethanolamine salt sold under the references ARLATONE MAP 230K-40® and ARLATONE MAP 230T-60® by Uniqema, potassium lauryl phosphate, marketed under the name Dermalcare XC-99 / 09® by the company Rhodia Chimie, and the potassium cetyl phosphate marketed under the name Arlatone MAP 160K by the company Uniqema. 10) The polypeptides are obtained for example by condensation of a fatty chain on the amino acids of cereals and in particular wheat and oats. Such polypeptides include, for example, the potassium salt of hydrolysed wheat lauroyl protein, marketed under the name AMINOFOAM W OR by the company Croda, the triethanolamine salt of cocoyl soy protein hydrolysed, sold under the name MAY- TEIN SY by the company Maybrook, the sodium salt of lauroyl amino acids of oats, sold under the name PROTEOL OAT by the company Seppic, the collagen hydrolyzate grafted on coconut fatty acid, marketed under the name GELIDERM 3000 by the company Deutsche Gelatin, soy proteins acylated with hydrogenated copra acids, sold under the name PROTEOL VS 22 by the company Seppic. 11) As the metal salts of C 10 -C 30 fatty acids, in particular C 12 -C 20, mention may in particular be made of metal stearates, such as sodium stearate and potassium stearate, as well as polyhydroxy stearates. Preferably, the composition according to the invention comprises at least one nonionic surfactant as stabilizing agent, preferably chosen from alkyl and polyalkyl esters of sorbitan, in particular non-polyoxyethylenated, and better still a mixture of stearate. sorbitan and sucrose cocoate, preferably that sold under the reference Arlacel 2121 from Croda; or else chosen from fatty alcohols, in particular having at least 8 carbon atoms, which are oxyalkylenated, in particular oxyethylenated and / or oxypropylenated, and may contain from 1 to 150 oxyethylene and / or oxypropylene units, in particular having from 20 to 100 oxyethylene units; , in particular fatty alcohols, especially C8-C24, and preferably C12-C18, ethoxylated, or mixtures thereof. Geminated surfactant According to a particularly advantageous variant of the invention, the composition 40 comprises at least one gemini surfactant of formula (I): ## STR1 ## in which: R1 and R3 denote, independently of one another, an alkyl radical having from 1 to 25 carbon atoms; R2 represents a spacer consisting of a linear or branched alkylene chain having from 1 to 12 carbon atoms; X and Y denote, independently of one another, a group - (C2H40) a (C3H60) bZ where - Z denotes a hydrogen atom or a radical -CH2-COOM, -SO3M, -P (0 ) (01 4) 2, -C2H4-SO3M, -C3H6-SO3M or -CH2 (CHOH) 4CH2OH, where M, M 'represent H or an alkaline or alkaline-earth ion or ammonium or alkanolammonium, - a va de 0 to 15, b is from 0 to 10, and the sum of a + b goes beyond 25; and n is from 1 to 10. The gemini surfactant of formula (I) is preferably such that each of the R1-CO- and R3-CO- groups comprises from 8 to 20 carbon atoms, and preferably denotes a radical. of coconut fatty acids (mainly comprising lauric acid and myristic acid). In addition, this surfactant is preferably such that, for each of the radicals X and Y, the sum of a and b has an average value ranging from 10 to 20 and is preferably equal to 15.
[0059] A preferred group for Z is the group -SO 3 M where M is preferably an alkaline ion such as sodium ion. The spacer R2 is advantageously constituted by a linear C 1 -C 3 alkylene chain, and preferably an ethylene chain (CH 2 CH 2). Finally, n is advantageously equal to 1.
[0060] A surfactant of this type is in particular that identified by the INCI name: Sodium dicocoylethylenediamine PEG-15 sulfate, having the following structure: ## STR11 ## (PEG-15) -SO3Na cocoyl -C -N CH2 CH2 cocoyl -C -N - - (PEG-15) -S 03Na II 0 it being understood that PEG represents the group CH2CH20, and cocoyl represents the rest of coconut fatty acids.
[0061] This surfactant has a molecular structure very close to that of ceramide-3.
[0062] Preferably, the geminate surfactant according to the invention is used in admixture with other surfactants, and in particular in admixture with (a) a C 6 -C 22 (preferably C 14 -C 20) fatty acid ester such as stearate) and glyceryl, (b) a C 6 -C 22 (preferably C 14 -C 20) fatty acid diester such as a stearate and citric acid and glycerol (especially a fatty acid diester). C6-C22 and glyceryl monitrate), and (c) a C10-C30 fatty alcohol (preferably behenyl alcohol). Advantageously, the composition according to the invention comprises a mixture of Sodium Dicocoylethylenediamine PEG-15 Sulfate, glyceryl stearate, glyceryl monitrate stearate, behenyl alcohol.
[0063] More preferably, the geminate surfactant according to the invention represents from 10 to 20% by weight, and advantageously 15% by weight; the fatty acid C 6 -C 22 and glyceryl ester represents from 30 to 40% by weight, advantageously 35% by weight; the C 6 -C 22 fatty acid diester and citric acid and glycerol represent from 10 to 20% by weight, advantageously 15% by weight; and the C 10 -C 30 fatty alcohol represents from 30 to 40% by weight, advantageously 35% by weight, based on the total weight of the surfactant mixture containing the geminate surfactant. Advantageously, the composition according to the invention comprises a mixture of 10 to 20% by weight of Sodium Dicocoylethylenediamine PEG-15 Sulfate, from 30 to 40% by weight of glyceryl stearate, from 10 to 20% by weight of monocrystalline stearate. Glyceryl, from 30 to 40% by weight of behenyl alcohol, relative to the total weight of the surfactant mixture containing the geminate surfactant. Alternatively, the geminate surfactant according to the invention may be used in admixture with an anionic surfactant such as a lauric acid ester, sodium lauroyl lactate. In this case, the gemini surfactant is preferably 30 to 50% by weight, and the anionic surfactant is 50 to 70% by weight, based on the total weight of the mixture. For example, the geminate surfactant can be used in admixture with other surfactants in the form of the products sold by SASOL under the names CERALUTION, and in particular the following products: Ceralution® H: Behenyl Alcohol, Glyceryl Stearate, Glyceryl Stearate Citrate and Sodium Dicocoylethylenediamine PEG-15 Sulfate, - Ceralution® F: Sodium Lauroyl Lactylate and Sodium Dicocoylethylenediamine PEG-15 Sulfate. Ceralution® C: Aqua, Capric / Caprylic triglyceride, Glycerin, Ceteareth-25, Sodium Dicocoylethylenediamine PEG-15 Sulfate, Sodium Lauroyl Lactylate, Behenyl Alcohol, Glyceryl Stearate, Glyceryl Stearate Citrate, Gum Arabic, Xanthan Gum, Phenoxyethanol, Methylparaben, Ethylparaben, Butylparaben, Isobutylparaben (INCI names). This gemini surfactant represents from 3 to 50% of the weight of these mixtures. Preferably, the composition comprises, as a gemini surfactant, the compound 40 don t the INCI name is Behenyl Alcohol, Glyceryl Stearate, Glyceryl Stearate Citrate and 3037794 33 Sodium Dicocoylethylenediamine PEG-15 Sulfate, sold under the name Ceralution® H by the company Sasol. According to a preferred embodiment of the invention, the composition comprises at least one anionic surfactant and at least one nonionic surfactant as defined above. According to a more particular variant of this embodiment, the composition further comprises at least one gemini surfactant of formula (I) detailed above.
[0064] More particularly, the content of anionic surfactant (s) present in the composition according to the invention represents from 0.1 to 2% by weight, preferably from 0.2 to 1.5% by weight. , relative to the weight of the composition. Preferably, the content of nonionic surfactant (s) present in the composition according to the invention represents from 0.5 to 10% by weight, preferably from 0.5 to 5% by weight, better from 1 to 5% by weight, relative to the weight of the composition. Preferably, if the composition comprises, the content of gemini surfactant of formula (I) is between 0.1 and 3% by weight, and even more particularly between 0.2 and 2% by weight, relative to the total weight of the composition.
[0065] ADDITIONAL COMPOUNDS A composition according to the invention may further comprise at least one additional compound selected from fillers, solid fatty substances, semi-crystalline polymers, film-forming polymers, and mixtures thereof.
[0066] Fillers A cosmetic composition used according to the invention may comprise at least one filler, of organic or mineral nature. By "charge" is meant colorless or white, solid particles of all shapes, which are in an insoluble form and dispersed in the medium of the composition. Of mineral or organic nature, they make it possible to impart body or stiffness to the composition, and / or softness, and uniformity to make-up. They are distinct from the dyestuffs Among the fillers that can be used in the compositions according to the invention, mention may be made of silica, kaolin, bentone, starch, lauroyl-lysine, fumed silica particles, optionally hydrophilic treated. or hydrophobic, and mixtures thereof. A composition used according to the invention may comprise one or more fillers in a content ranging from 0.1% to 15% by weight, in particular from 1% to 10% by weight relative to the total weight of the composition.
[0067] Advantageously, a solid fatty substance is represented by at least one wax. Thus, the composition according to the invention may also comprise at least one wax. For the purposes of the invention, the term "wax" means a lipophilic compound, solid at room temperature (25 ° C.), with reversible solid / liquid state change, having a melting point of greater than or equal to 30 ° C. C up to 120 ° C. The waxes that may be used in a composition according to the invention are chosen from waxes, solid, deformable or not at room temperature, of animal, vegetable, mineral or synthetic origin, and mixtures thereof.
[0068] For example, solid fatty alcohols comprising from 10 to 24 carbon atoms, and more preferably from 12 to 22 carbon atoms, may be mentioned. As particular examples of fatty alcohols that may be used as preferred, particular mention may be made of myristic, palmitic, behenic, erucic and arachidyl alcohol, and mixtures thereof. In particular, hydrocarbon waxes such as beeswax, lanolin wax, and Chinese insect waxes may be used; rice wax, Carnauba wax, Candelilla wax, Ouricurry wax, Alfa wax, cork fiber wax, sugar cane wax, Japanese wax and sumac wax ; montan wax, microcrystalline waxes, paraffins and ozokerite; polyethylene waxes, waxes obtained by Fisher-Tropsch synthesis and waxy copolymers and their esters.
[0069] There may also be mentioned waxes obtained by catalytic hydrogenation of animal or vegetable oils having linear or branched C8-C32 fatty chains. Among these, there may be mentioned hydrogenated jojoba oil, hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut oil and hydrogenated lanolin oil, di-tetrastearate ( trimethyl-1-1,1,1-propane) sold under the name "HEST 2T-4S" by the company HETERENE, di (1,1,1-trimethyltrimethylolpropane) tetraprenate sold under the name HEST 2T-4B by the company HETERENE. It is also possible to use the waxes obtained by transesterification and hydrogenation of vegetable oils, such as castor oil or olive oil, such as the waxes sold under the names Phytowax castor 16L64® and 22L73® and Phytowax Olive 18L57 by the SOPHIM company. Such waxes are described in application FR-A-2792190. It is also possible to use silicone waxes which may advantageously be substituted polysiloxanes, preferably at low melting point. Among the commercial silicone waxes of this type, mention may be made especially of those sold under the names Abilwax 9800, or 9810 (GOLDSCHMIDT), KF910 and KF7002 (SHIN ETSU), or 176-1118-3 and 176-11481 (GENERAL ELECTRIC ). The silicone waxes that may be used may also be alkyl or alkoxydimethicones such as the following commercial products: Abilwax 2428, 2434 and 2440 (GOLDSCHMIDT), or VP 1622 and VP 1621 (WACKER), as well as (C20-C6o) alkyl dimethicones, in particular (C30-C45) alkyldimethicones such as the silicone wax sold under the name SF-1642 by the company GE-Bayer Silicones. It is also possible to use hydrocarbon waxes modified with silicone or fluorinated groups such as, for example, siliconyl candelilla, siliconyl beeswax and Fluorobeeswax by Koster Keunen.
[0070] The waxes may also be selected from fluorinated waxes. According to a preferred embodiment, a composition according to the invention may comprise at least one wax having a melting point of less than 65 ° C., preferably less than 63 ° C.
[0071] Such a wax may in particular be chosen from paraffin wax, stearic alcohol, hydrogenated coco-glycerides, synthetic beeswax (in particular that marketed under the reference CYCLOCHEM 326 A by Evonik Goldschmidt), butter of palm, Sumac wax, silicone beeswax, stearyl stearate, dimethicone alkyl wax, certain polymethylene waxes (such as Cirebelle's market-made wax 303), berry wax, coconut oil waxes and the like. olive, lemon wax, ceresin wax (sold under the reference WHITE CERESIN WAX JH 520 by HANSOTECH), and mixtures thereof. According to an even more preferred embodiment, a composition according to the invention may comprise at least one hydrogenated olive oil ester wax, preferably that whose INCI name is HYDROGENATED STEARYL OLIVE ESTERS, such as that sold under the reference PHYTOWAX OLIVE 18 L 57 of SOPHIM and that whose INCI name is HYDROGENATED MYRISTYL OLIVE ESTERS, such as the one sold under the reference PHYTOWAX OLIVE 14L48 of SOPHIM.
[0072] According to one embodiment, the composition according to the invention is free of wax. According to another embodiment, the composition according to the invention may comprise an additional wax content (s) with a melting point of less than 65 ° C. ranging from 0.1 to 10% by weight and better still from 0 , 5% to 5% by weight, relative to the total weight of the composition.
[0073] In particular, the composition according to the invention may comprise a total wax content of between 0.1% and 30% by weight, relative to the total weight of the composition. Preferably, the composition according to the invention may comprise between 0.1 and 20% by weight of wax (s), more particularly between 0.5 and 15% by weight, and better still between 1 and 10% by weight, relative to to the total weight of the composition.
[0074] Preferably, when the composition is in liquid form, it comprises a total wax content of between 0.1% and 5% by weight, relative to the total weight of the composition. Advantageously, the solid fatty substance is represented by a pasty fatty substance. This embodiment is particularly advantageous in the case where one seeks to obtain a gloss or satin deposit, such as in the makeup product of the lips, such as a lipstick.
[0075] Thus, the composition considered according to the invention may further comprise at least one pasty fatty substance. For the purposes of the present invention, the term "pasty fatty substance" is intended to mean a lipophilic fat compound with a reversible solid / liquid state change, having in the solid state an anisotropic crystalline organization and having at a temperature of 23 ° C. a liquid fraction and a solid fraction. In other words, the starting melting temperature of the pasty compound may be less than 23 ° C. The liquid fraction of the pasty compound measured at 23 ° C. can represent 9 to 97% by weight of the compound. This liquid fraction at 23 ° C is preferably between 15 and 85%, more preferably between 40 and 85% by weight.
[0076] Within the meaning of the invention, the melting temperature corresponds to the temperature of the most endothermic peak observed in thermal analysis (DSC) as described in the ISO 11357-3 standard; 1999. The melting point of a paste or a wax can be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name "MDSC 2920" by the company TA Instruments .
[0077] The measurement protocol is as follows: A sample of 5 mg of paste or wax (as the case may be) placed in a crucible is subjected to a first temperature rise from -20 ° C. to 100 ° C., at a rate of 10 ° C / minute, then cooled from 100 ° C to -20 ° C at a cooling rate of 10 ° C / minute and finally subjected to a second temperature rise from -20 ° C to 100 ° C. ° C at a heating rate of 5 ° C / minute. During the second temperature rise, the variation of the power difference absorbed by the empty crucible and the crucible containing the pasty or wax sample is measured as a function of temperature. The melting point of the compound is the value of the temperature corresponding to the peak apex of the curve representing the variation of the difference in power absorbed as a function of temperature. The liquid fraction by weight of the pasty compound at 23 ° C. is equal to the ratio of the enthalpy of fusion consumed at 23 ° C. to the heat of fusion of the pasty compound. The enthalpy of fusion of the pasty compound is the enthalpy consumed by the compound 35 to change from the solid state to the liquid state. The pasty compound is said to be in the solid state when the entirety of its mass is in crystalline solid form. The pasty compound is said to be in a liquid state when all of its mass is in liquid form. The enthalpy of fusion of the pasty compound is equal to the area under the curve of the thermogram obtained using a differential scanning calorimeter (DS C), such as the 40 calorimeter sold under the name MDSC 2920 by the company TA instrument, with a temperature rise of 5 or 10 ° C per minute, according to ISO 11357-3: 1999. The enthalpy of fusion of the pasty compound is the amount of energy required to pass the compound from the solid state to the liquid state. It is expressed in J / g. The enthalpy of fusion consumed at 23 ° C. is the amount of energy absorbed by the sample to change from the solid state to the state that it has at 23 ° C. consisting of a liquid fraction and a solid fraction. The liquid fraction of the pasty compound measured at 32 ° C is preferably 30 to 100% by weight of the compound, preferably 50 to 100%, more preferably 60 to 100% by weight of the compound. When the liquid fraction of the pasty compound measured at 32 ° C is 100%, the temperature of the end of the melting range of the pasty compound is less than or equal to 32 ° C. The liquid fraction of the pasty compound measured at 32 ° C. is equal to the ratio of the enthalpy of fusion consumed at 32 ° C. to the heat of fusion of the pasty compound. The heat of fusion consumed at 32 ° C. is calculated in the same way as the heat of fusion consumed at 23 ° C. The pasty fatty substance may be chosen from synthetic compounds and compounds of plant origin. A pasty fatty substance can be obtained synthetically from starting materials of plant origin. The pasty fatty substance is advantageously chosen from: lanolin and its derivatives such as lanolin alcohol, oxyethylenated lanolines, acetylated lanolin, lanolin esters such as isopropyl lanolate, oxypropylenated lanolines, polymeric or non-polymeric silicone compounds, such as high molecular weight polydimethysiloxanes, alkyl or alkoxy side chain polydimethylsiloxanes having 8 to 24 carbon atoms, especially stearyl dimethicones, - polymeric or non-polymeric fluorinated compounds, vinyl polymers, in particular: homopolymers of olefins, olefin copolymers, homopolymers and copolymers of hydrogenated dienes, linear or branched oligomers, homo or copolymers of alkyl (meth) acrylates having preferably a C8-C30 alkyl group, homo- and copolymeric oligomers of vinyl esters having α-groups; C8-C30 alkyls, homo- and copolymeric oligomers of vinyl ethers having C8-C30 alkyl groups, liposoluble polyethers resulting from the polyetherification between one or more C2-C10, preferably C2-C50 diols, esters and polyesters, and mixtures thereof. The pasty fatty substance may be a polymer, in particular a hydrocarbon polymer. A preferred silicone and fluoro pasty fatty substance is polymethyl-trifluoropropylmethylalkyl dimethylsiloxane, manufactured under the name X22-1088 by Shin Etsu.
[0078] Among the liposoluble polyethers, there may be mentioned copolymers of ethylene oxide and / or propylene oxide with C6-C3 alkylene oxides. Preferably, the weight ratio of ethylene oxide and / or propylene oxide to the alkylene oxides in the copolymer is from 5:95 to 70:30. In this family, block copolymers comprising blocks of C 6 -C 30 alkylene oxides having a molecular weight ranging from 1,000 to 10,000, for example a polyoxyethylene / polydodecylene glycol block copolymer such as the ethers of dodecanediol (22 mol) and polyethylene glycol (45 oxyethylene or 0E units) marketed under the trademark ELFACOS ST9 by Akzo Nobel. Among the esters, the following are particularly preferred: esters of an oligomeric glycerol, in particular the diglycerol esters, in particular the adipic acid and glycerol condensates, for which part of the hydroxyl groups of the glycerols have reacted with a mixture of fatty acids such as stearic acid, capric acid, stearic acid, isostearic acid and 12-hydroxystearic acid, for example those sold under the trade name Softisan 649 by the company Sasol; or having reacted with a mixture of fatty acids such as lauric acid, palmitic acid, cetyl acid and stearic acid, for example those sold under the reference Softisan 100 by Cremer Oleo: phytosterol esters; pentaerythritol esters; Esters formed from: at least one C16-40 alcohol, at least one of the alcohols being a Guerbet alcohol and a diacid dimer formed from at least one unsaturated fatty acid at C18-40, such as tall oil fatty acid dimer ester having 36 carbon atoms and a mixture of i) Guerbet alcohols having 32 carbon atoms and ii) behenyl alcohol; the dimer ester of linoleic acid and a mixture of two Guerbet alcohols, 2-tetradecyl-octadecanol (32 carbon atoms) and 2-hexadecyl-eicosanol (36 carbon atoms); Non-crosslinked polyesters resulting from the polycondensation between a linear or branched C 4 -C 50 dicarboxylic acid or polycarboxylic acid and a C2-C50 diol or polyol - the polyesters which result from the esterification between an acid polycarboxylic acid and an aliphatic hydroxyl carboxylic acid ester such as Risocast DA-L and Risocast DA-H marketed by the Japanese company KOKYU ALCOHOL KOGYO, 3037794 39 which are esters resulting from the esterification reaction of the oil of hydrogenated castor with dilinoleic acid or isostearic acid; and the aliphatic ester esters resulting from the esterification between an aliphatic hydroxyl carboxylic acid ester and an aliphatic carboxylic acid, for example that sold under the trade name Salacos HCIS (V) -L by the company Nishing Oil. Guerbet alcohol is the reaction product of the Guerbet reaction well known to those skilled in the art. It is a reaction transforming a primary aliphatic alcohol into its dimer alcohol (3-alkylated with loss of one equivalent of water.
[0079] The aliphatic carboxylic acids described above generally comprise from 4 to 30 and preferably from 8 to 30 carbon atoms. They are preferably chosen from hexanoic acid, heptanoic acid, octanoic acid, 2-ethylhexanoic acid, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, hexyldecanoic acid, heptadecanoic acid, octadecanoic acid, isostearic acid, nonadecanoic acid, eicosanoic acid, isoarachidic acid, octyldodecanoic acid, henicosanoic acid, docosanoic acid, and mixtures thereof. The aliphatic carboxylic acids are preferably branched.
[0080] The hydroxylated aliphatic carboxylic acid esters are advantageously derived from a hydroxylated aliphatic carboxylic acid having from 2 to 40 carbon atoms, preferably from 10 to 34 carbon atoms and better still from 12 to 28 carbon atoms, and from 1 to to 20 hydroxyl groups, preferably 1 to 10 hydroxyl groups and more preferably 1 to 6 hydroxyl groups. The hydroxylated aliphatic carboxylic acid esters are especially chosen from: a) the esters, partial or total, of saturated linear monohydroxylated aliphatic monocarboxylic acids; b) esters, partial or total, of unsaturated monohydroxylated aliphatic monocarboxylic acids; C) the esters, partial or total, of saturated monohydroxylated aliphatic polycarboxylic acids; d) the esters, partial or total, of saturated polyhydroxylated aliphatic polycarboxylic acids; e) esters, partial or total, of C 2 to C 16 aliphatic polyols reacted with a mono- or polyhydroxylated aliphatic mono- or polycarboxylic acid, f) and mixtures thereof. the diol dimer and diacid dimer esters, where appropriate, esterified on their (their) alcohol (s) or free acid (s) function (s) with acidic or alcoholic groups, in particular dimer dilinoleate esters; such esters may be chosen in particular from the following INCI nomenclature esters: bis-behenyl / isostearyl / phytosteryl dimerdilinoleyl dimerdilinoleate (Plandool G), phytosteryl / isosteryl / cetyl / stearyl / behenyl dimerdilinoleate (Plandool H or Plandool S) ) and their mixtures, vegetable butters such as mango butter, such as that marketed under the reference Lipex 203 by Aharhuskarlshamn, shea butter, in particular the one whose INCI name is Butyrospermum Parkii Butter, such as that sold under the reference Sheasoft® by AARHUSKARLSHAMN, cupuacu butter (Rain Forest RF3410 from Beraca Sabara), murumuru butter (RAIN FOREST RF3710 from Beraca Sabara), cocoa butter; as well as orange wax such as, for example, that marketed under the reference Orange Peel Wax by the company Koster Keunen, - vegetable oils which are totally or partially hydrogenated, such as, for example, hydrogenated soybean oil, hydrogenated coconut oil, hydrogenated rapeseed oil, hydrogenated vegetable oil mixtures such as the mixture of hydrogenated vegetable oil of soybean, coconut, palm and rapeseed, for example the mixture marketed under the reference Akogel® by the AARHUSKARLSHAMN company (INCI name Hydrogenated Vegetable Oil), trans isomerized partially hydrogenated jojoba oil manufactured or marketed by the company Desert Whale under the trade reference Iso-Jojoba-50®, partially hydrogenated olive oil as, for example , the compound sold under the reference Beurrolive by the company Soliance.
[0081] The ester aliphatic esters are advantageously chosen from: the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid in the proportions 1 to 1 (1/1), which is called hydrogenated castor oil monoisostearate; - the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid in proportions 1 to 2 (1/2), which is called diisostearate d hydrogenated castor oil, - the ester resulting from the esterification reaction of hydrogenated castor oil with isostearic acid in the proportions 1 to 3 (1/3), which is called the oil triisostearate of hydrogenated castor, - and mixtures thereof. In particular, the composition according to the invention may comprise a total pasty fatty substance content of between 0.1% and 30% by weight relative to the total weight of the composition. Preferably, the pasty fatty substance (s) may be present in an amount ranging from 0.5% to 30% by weight, especially from 1% to 20% by weight, relative to the total weight of the composition. In a first embodiment, the composition may further comprise at least one additional moisturizing agent (also called humectant), different from glycerine. Additional humectant or moisturizing agents that may be mentioned include sorbitol, urea and its derivatives, in particular Hydrovance (2-hydroxyethyl urea) marketed by National Starch, lactic acids, hyaluronic acid, AHAs and BHAs. , sodium pidolate, xylitol, serine, sodium lactate, ectoin and its derivatives, chitosan and its derivatives, collagen, plankton, an extract of imperata cylindra marketed under the name Moist 24 by the Sederma company, homopolymers of acrylic acid such as NOF corporation Lipidure-HM®, beta-glucan and in particular sodium carboxymethyl beta-glucan from Mibelle-AG-Biochemistry; a mixture of passionflower, apricot, corn and rice bran oils marketed by Nestlé under the name NutraLipids®; a C-glycoside derivative such as those described in patent application WO 02/051828 and in particular CPD-xylopyranoside-2-hydroxy-propane in the form of a solution containing 30% by weight of active material in a water / propylene mixture glycol (60/40% by weight) such as the product manufactured by CHIMEX under the trade name "MEXORYL SBB °"; a muscat rose oil marketed by Nestlé; an extract of microalga Prophyridium cruentum enriched in zinc marketed by Vincience under the name Algualane Zinc®; spheres of collagen and chondroitin sulfate of marine origin (Ateocollagen) marketed by Engelhard Lyon under the name marine filling spheres; spheres of hyaluronic acid such as those marketed by Engelhard Lyon; and arginine. Preferably, use will be made of a moisturizing agent chosen from glycerin, urea and its derivatives, in particular Hydrovance® marketed by National Starch, hyaluronic acid, AHAs, BHAs, homopolymers of acrylic acid such as Lipidure -HM® from NOF Corporation, beta-glucan and in particular sodium carboxymethyl beta-glucan from Mibelle-AG-Biochemistry; a blend of passionflower, apricot, corn, and rice bran oils marketed by Nestlé under the name NutraLipids®; a C-glycoside derivative such as those described in patent application WO 02/051828 and in particular CPD-xylopyranoside-2-hydroxypropane in the form of a solution containing 30% by weight of active material in a water / propylene glycol mixture (60/40% by weight) such as the product manufactured by CHIMEX under the trade name "MEXORYL SBB °"; a muscat rose oil marketed by 35 Nestlé; an extract of microalga Prophyridium cruentum enriched in zinc marketed by Vincience under the name Algualane Zinc®; spheres of collagen and chondroitin sulfate of marine origin (Ateocollagen) marketed by Engelhard Lyon under the name marine filling spheres; spheres of hyaluronic acid such as those marketed by Engelhard Lyon; and 40 arginine.
[0082] AQUEOUS PHASE As stated above, a composition according to the invention comprises at least 5% by weight of water, preferably at least 10% by weight of water, relative to the total weight of the composition.
[0083] Preferably, a composition according to the invention may comprise from 5% to 80% by weight of water, preferably from 10% to 70% by weight, in particular from 15% to 60% by weight, in particular from 15% to 50% by weight, more particularly 20 to 50% by weight, based on its total weight. The composition according to the invention may comprise, in addition to water, at least one water-soluble solvent. The aqueous phase may constitute the continuous phase of the composition. By aqueous continuous phase composition is meant that it is possible to measure a pH value for the composition with a suitable electrode (for example a Mettler Toledo MPC227 conductivity meter). As an indication, the pH of the composition is between 6.5 and 7.5. By "water-soluble solvent" is meant in the present invention a liquid compound at room temperature and miscible with water (miscibility in water greater than 50% by weight at 25 ° C and atmospheric pressure). The water-soluble solvents that can be used in the compositions according to the invention can moreover be volatile. Among the water-soluble solvents that can be used in the compositions in accordance with the invention, there may be mentioned lower monoalcohols having from 1 to 5 carbon atoms such as ethanol and isopropanol, C3 and C4 ketones and aldehydes. in C2-C4.
[0084] Preferably, the composition according to the invention preferably comprises a total content of monoalcohols comprising between 2 and 8 carbon atoms of between 0 and 10% by weight (limits included) relative to the total weight of the composition. Preferably, the composition according to the invention comprises a total content of monoalcohols comprising between 2 and 8 carbon atoms of between 0 and 5% by weight (limits included) relative to the total weight of the composition. Preferably, the composition according to the invention is free of monoalcohols comprising between 2 and 8 carbon atoms. Preferably, said mono-alcohol (s) comprising between 2 and 8 carbon atoms is / are chosen from ethanol, butanol, methanol or isopropanol. However, the content in the aqueous phase above indicated does not include the contents of each of the compounds raised. A composition according to the invention may furthermore comprise any additional component usually used in cosmetics, such as dyestuffs, fillers or cosmetic actives.
[0085] Of course, those skilled in the art will take care to choose the optional additional compounds, and / or their quantity, in such a way that the advantageous properties of the composition used according to the invention are not, or not substantially, impaired by the proposed adjunction.
[0086] COLORING USES A composition according to the invention preferably comprises at least one dyestuff. Preferably, it is chosen from water-soluble or non-fat soluble or non-soluble, organic or inorganic dyestuffs, optical effect materials, and mixtures thereof. For the purposes of the present invention, the term "dyestuff" means a compound capable of producing a colored optical effect when it is formulated in sufficient quantity in a suitable cosmetic medium. According to a preferred embodiment, a composition according to the invention comprises at least one water-soluble dyestuff. The water-soluble dyestuffs used according to the invention are more particularly water-soluble dyes. For the purposes of the invention, the term "water-soluble dye" is intended to mean any generally organic compound, natural or synthetic, soluble in an aqueous phase, or water-miscible and color-capable solvents. In particular, it is intended to characterize, by the term water-soluble, the ability of a compound to solubilize in water, measured at 25 ° C., at a concentration of at least 0.1 g / l (obtaining a macroscopically isotropic and transparent solution, colored or not). This solubility is in particular greater than or equal to 1 g / l.
[0087] As water-soluble dyes suitable for the invention, mention may in particular be made of synthetic or natural water-soluble dyes such as, for example, FDC Red 4 (CI: 14700), DC Red 6 (Lithol Rubine Na, CI: 15850), DC Red 22 (CI: 45380), DC Red 28 (CI: 45410 Na salt), DC Red 30 (CI: 73360), DC Red 33 (CI: 17200), DC Orange 4 (CI: 15510) , FDC Yellow 5 (CI: 19140), FDC Yellow 6 (CI: 15985), DC Yellow 8 (CI: 45350 Na salt), FDC Green 3 (CI: 42053), DC Green 5 (CI : 61570), FDC Blue 1 (CI: 42090). By way of non-limiting illustration of sources of water-soluble dye (s) that may be used in the context of the present invention, mention may be made especially of those of natural origin, such as extracts of carmine, cochineal, beetroot, grape, carrot, tomato, annatto, paprika, henna, caramel and curcumin. Thus, the water-soluble dyestuffs that are suitable for use in the invention are in particular carminic acid, betanine, anthocyanins, enocyanines, lycopene, beta-carotene, bixin, norbixin, capsanthin, capsorubin, flovoxanthin, 3037794 Lutein, cryptoxanthin, rubixanthine, violaxanthin, riboflavin, roudoxanthin, cantaxanthin, chlorophyll, and mixtures thereof. It may also be copper sulfate, iron, water-soluble sulfopolyesters, rhodamine, betaine, methylene blue, disodium tartrazine salt and disodium fuschine salt. Some of these water-soluble dyestuffs are in particular approved for food. As a representative of these dyes, mention may be made more particularly of the dyes of the family of carotenoids, referenced under the food codes E120, E162, E163, E160a-g, E150a, E101, E100, E140 and E141.
[0088] According to a preferred variant, the water-soluble coloring substance (s) to be transferred onto the skin and / or the lips to be made up, are formulated in a physiologically acceptable medium. so as to be compatible with impregnation at the substrate.
[0089] The water-soluble dyestuff (s) may be present in a composition according to the invention in a content ranging from 0.01 to 8% by weight, preferably from 0.1 to 6% by weight, relative to the total weight of said composition According to a particularly preferred embodiment, the water-soluble dyestuff (s) are chosen from the di-sodium salt of the brilliant yellow FCF sold by the company LCW under the name DC Yellow 6, the di-sodium salt of acid fuchsin D marketed by LCW under the name DC Red 33, the tri-sodium salt Allura Red marketed by LCW under the denomination FD & C Red 40.
[0090] According to one particular embodiment of the invention, the composition according to the invention comprises only water-soluble dyes as dyestuffs. According to another embodiment, a composition according to the invention may comprise, in addition to the water-soluble dyestuffs described above, one or more additional dyestuffs, in particular fat-soluble dyes, or dyestuffs of the pigment or nacre type conventionally used in cosmetic compositions. Among the liposoluble dyes, mention may be made especially of fluoran type dyes such as, for example, Red 21 or Red 27, or mixtures thereof.
[0091] By pigments, it is necessary to include white or colored, inorganic (mineral) or organic particles, insoluble in the liquid organic phase, intended to color and / or opacify the composition and / or the deposition carried out with the composition.
[0092] The pigments may be chosen from inorganic pigments, organic pigments, and composite pigments (that is to say pigments based on mineral and / or organic materials). The pigments may be chosen from monochromatic pigments, lacquers, pearlescent agents, optical effect pigments, such as reflecting pigments and goniochromatic pigments. The inorganic pigments may be chosen from metal oxide pigments, chromium oxides, iron oxides, titanium dioxide, zinc oxides, cerium oxides, zirconium oxides, manganese violet, prussian blue, ultramarine blue, ferric blue, and mixtures thereof. The organic pigments may be, for example: cochineal carmine, organic pigments of azo, anthraquinone, indigo, xanthene, pyrenic, quinoline, triphenylmethane or fluoran dyes; Organic lakes or insoluble salts of sodium, potassium, calcium, barium, aluminum, zirconium, strontium, titanium, acid dyes such as azo, anthraquinone, indigo, xanthene, pyrenic dyes, quinolinic, triphenylmethane, fluoran. These dyes generally comprise at least one carboxylic or sulphonic acid group; Melanic pigments. Among the organic pigments, mention may be made of D & C Blue No. 4, D & C Brown No. 1, D & C Green No. 5, D & C Green No. 6, D & C Orange No. 4, D & C Orange No. 5, D & C Orange No. 10 , D & C Orange No. 11, D & C Red No. 6, D & C Red No. 7, D & C Red No. 17, D & C Red No. 21, 25 D & C Red No. 22, D & C Red No. 27, D & C Red No. 28, D & C Red No. 30, D & C Red No. 31, D & C Red No. 33, D & C Red No. 34, D & C Red No. 36, D & C Violet No. 2, D & C Yellow No. 7, D & C Yellow No. 8, D & C Yellow No. 10, D & C Yellow No. 11, FD & C Blue No. 1, FD & C Green No. 3, FD & C Red No. 40, FD & C Yellow No. 5, FD & C Yellow No. 6.
[0093] The hydrophobic treatment agent may be selected from silicones such as methicones, dimethicones, perfluoroalkylsilanes; fatty acids such as stearic acid; metal soaps such as aluminum dimyristate, hydrogenated tallow glutamate aluminum salt, perfluoroalkyl phosphates, perfluoroalkyl silanes, perfluoroalkyl silazanes, hexafluoropropylene polyoxides, polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups, amines; N-acyl amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof. The N-acyl amino acids may comprise an acyl group having 8 to 22 carbon atoms, such as, for example, 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl, cocoyl. The salts of these compounds may be the salts of aluminum, magnesium, calcium, zirconium, zin, sodium or potassium. The amino acid can be for example lysine, glutamic acid, alanine. The term alkyl mentioned in the compounds mentioned above denotes in particular an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 carbon atoms. Hydrophobic-treated pigments are described in particular in application EP-A-1086683. For the purposes of the present application, the term "mother-of-pearl" means colored particles of any shape, iridescent or otherwise, especially produced by certain shellfish in their shell or else synthesized and which exhibit a color effect by optical interference. Examples of pearlescent agents that may be mentioned are pearlescent pigments such as iron oxide-coated titanium mica, bismuth oxychloride-coated mica, titanium mica coated with chromium oxide, titanium mica coated with a organic dye 15 especially of the aforementioned type as well as pearlescent pigments based on bismuth oxychloride. It may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic dyestuffs. The nacres may more particularly have a yellow, pink, red, bronze, orange, brown, gold and / or copper color or reflection. As an illustration of nacres that can be introduced as interference pigment in the first composition, mention may be made of gold-colored pearlescent agents marketed by ENGELHARD under the name Brillant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), Gold 4504 (Chromalite) and Monarch gold 25 233X (Cloisonne); bronze nacres sold especially by the company Merck under the name Bronze Fine (17384) (Colorona) and Bronze (17353) (Colorona) and by Engelhard under the name Super Bronze (Cloisonne); orange nacres sold especially by ENGELHARD under the name Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by MERCK under the name Passion orange (Colorona) and Matte orange (17449) (Microna); brown-colored pearlescent agents marketed by Engelhard under the name Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); nacres with a copper sheen sold especially by Engelhard under the name Copper 340A (Timica); the red-colored pearlescent agents marketed by MERCK under the name Sienna fine (17386) (Colorona); yellow-colored pearlescent agents marketed by ENGELHARD under the name Yellow (4502) (Chromalite); the red-colored pearlescent agents with a gold glint sold especially by ENGELHARD under the name Sunstone G012 (Gemtone); pink nacres sold especially by ENGELHARD under the name Tan opal G005 (Gemtone); the black nacres 3037794 47 black with gold glare sold by the company Engelhard under the name Nu antique bronze 240 AB (Timica), the blue nacres sold especially by the company Merck under the name Matte Blue (17433) (Microna), the white nacres with silvery reflection in particular marketed by the company 5 MERCK under the name Xirona Silver and pinkish orange-green gold nacres sold especially by Merck under the name Indian summer (Xirona) and mixtures thereof. ADDITIONAL USUAL COSMETIC INGREDIENTS A composition according to the invention may furthermore comprise any usual cosmetic ingredient that may be chosen in particular from antioxidants, additional film-forming polymers (lipophilic or hydrophilic), distinct from alkycellulose and in particular from ethylcellulose. perfumes, preservatives, neutralizers, sunscreens, sweeteners, vitamins, anti-free radical agents, sequestering agents, and mixtures thereof. Of course, those skilled in the art will take care to choose any additional ingredients and / or their quantity so that the advantageous properties of the composition according to the invention are not or not substantially impaired by the adj ulation envisaged.
[0094] According to one particular embodiment, a composition according to the invention may advantageously comprise: from 4 to 20% by weight of alkylcellulose, preferably ethylcellulose, from 15 to 60% by weight of water, from 5 to 50% by weight of a first non-volatile hydrocarbon oil, and even more preferably a C 10 -C 26 alcohol, from 5 to 60% by weight of non-volatile silicone oils, from 2 to 20% by weight at least one hydrocarbon resin having a number average molecular weight of less than or equal to 10 000 g / mol, in particular a hydrogenated indene / methylstyrene / styrene copolymer. A composition according to the invention may be more particularly a composition for makeup and / or care of keratin materials, in particular the skin and / or lips, and better lips.
[0095] A composition according to the invention may be a liquid lipstick for the lips, a body makeup product, a facial or body care product or an antisolar product. According to a preferred embodiment, a composition of the invention is in liquid form. As an illustration of the liquid formulations, mention may be made especially of lip gloss and / or, more generally, liquid lipsticks.
[0096] According to a preferred embodiment, a composition of the invention is a liquid lipstick. The composition according to the invention can be manufactured by known methods, generally used in the cosmetic or dermatological field.
[0097] Throughout the description, including the claims, the phrase "having one" should be understood as being synonymous with "having at least one", unless the opposite is specified. The terms "between ... and ..." and "from" must be understood inclusive unless the contrary is specified. The following examples and figures are presented for illustrative and non-limiting purposes of the invention.
[0098] EXAMPLES Example 1 The composition is prepared, the list of ingredients of which is indicated in Table 20 below (unless otherwise indicated, the contents are expressed in weight of raw material): Phase Ingredient Content A Ethylcellulose (dispersion in water - 30% solids, containing ethylcellulose, sodium lauryl sulfate, cetyl alcohol, AQUACOAT ECD 30 from FMC Biopolymer) 313 To Octyldodecanol 25.9 A Hydrogenated Styrene / Methyl Styrene / Indene Copolymer (REGALITE R1100 CG Hydrocarbon Resin, Eastman) 7.8 B1 Sorbitan Stearate - Sucrose Cocoate (ARLACEL 2121 U-FL, Croda) 3.8 B2 Hydroxypropyl guar (Jaguar HP 105, - Solvay) 0.2 F Diphenylsiloxyphenyl trimethicone (KF 56 A , Shin Etsu) 219 G1 Red 33 0.04 3037794 49 G1 Yellow 6 0.22 G1 water QS 100 G2 Red 7 0.8 H Preservative 0.7 H Ethanol 96 ° 3.3 Procedure 1 / Phase A is prepared by mixing at 110 ° C the hydrocarbon resin (Regalite) with most of the octyldo decanol and allowed to warm to room temperature: 2 / Then add the ethylcellulose with Rayneri stirring at 50-55 ° C to 1500trm. The sorbitan stearate / sucrose cocoate mixture is then added with stirring until completely dissolved. 4 / The hydroxypropyl guar is introduced until a homogeneous mixture is obtained, followed by diphenylsiloxyphenyl trimethicone with vigorous stirring which is maintained until the mixture is homogenized. It is allowed to return to room temperature. 5 / Then introduced water, ethanol, preservatives and dyes (G1 phase), with stirring, to disperse the dyes. 6 / The mixture of Red 7 is then added with stirring with the remaining portion of octyldodecanol (phase G2). A homogeneous, stable and fluid composition is obtained. The application of the composition on the lips is easy and one obtains a comfortable deposit, of homogeneous thickness, brilliant and covering. The composition migrates very little after one hour. The evaluation of the color fastness is carried out by means of a device Chromasphère Samba, on 6 models. A measurement is made directly after the application of the composition (10 minutes) and after holding tests (eating half an apple, 10 bites of sandwich, a hot or cold drink) and the measurement is redone. The difference in color (in%) is then calculated between the measurements before and after the tests.
[0099] It is found that a composition in accordance with the invention (Example 1) gives a significantly improved color fastness, compared to a composition in which the hydrocarbon resin has been replaced by the same content of octyldodecanol.
[0100] EXAMPLE 2 The following composition is prepared (contents expressed in% by weight of active ingredient, unless otherwise indicated). Phase Ingredients content A Ethylcellulose (dispersion in water - 30% solids, containing ethylcellulose, lauryl sulphate) sodium, cetyl alcohol, AQUACOAT ECD 30 from FMC Biopolymer) 313 To Octyldodecanol 27.8 A 'Hydrogenated Styrene / Methyl Styrene / Indene Copolymer (REGALITE R1100 CG Hydrocarbon Resin, Eastman) 5 B1 Sorbitan Stearate - Sucrose Cocoate (ARLACEL 2121 U-FL, Croda) 3.8 B2 Hydroxypropyl guar (Jaguar HP 105, Solvay) 0.2 F Trimethylsiloxyphenyl dimethicone (BELSIL® PDM 1000. Wacker) 21.9 G1 Red 33 0.04 G1 Yellow 6 0 , 22 G1 Water qs 100 G2 Red 7 0.5 H Preservative 0.7 H Ethanol 96 ° 3.3 10 Procedure The procedure is as for the preceding example. A homogeneous, stable and fluid composition is obtained. The application of the composition to the lips is easy and a comfortable deposit of homogeneous, glossy and covering thickness is obtained. The composition migrates very soon after one hour. The composition also has good color fastness (Samba chromasphere test).
[0101] Example 3 The following composition is prepared (contents expressed in% by weight of active ingredient, unless otherwise indicated); phase Ingredients contents Ethylcellulose (dispersion in water - 30% solids, containing ethylcellulose, sodium lauryl sulfate, cetyl alcohol, AQUACOAT ECD 30 from FMC Biopolymer) 31.3 A Octyldodecanol 20 A Hydrogenated Styrene / Methyl Styrene / Indene Copolymer (REGALITE R1100 CG Hydrocarbon Resin, Eastman) 78 B1 Sorbitan Stearate - Sucrose Cocoate (ARLACEL 2121 U-FL, Croda) 3.8 B2 Hydroxypropyl guar (Jaguar HP 105, - Solvay) 0.2 F Trimethylsiloxyphenyl dimethicone (BELSIL® PDM 1000. Wacker) 219 F Diphenylsiloxyphenyl trimethicone (KF 56 A, Shin Etsu) 5 G1 Yellow 6 0.22 G1 Red 33 0.04 G1 Water qs 100 G2 Red 7 0.5 H Preservative 0.7 H Ethanol 96 ° 3.3 5 Procedure The procedure is as for the preceding example. A homogeneous, stable and fluid composition is obtained. The application of the composition to the lips is easy and a comfortable deposit of homogeneous, glossy and covering thickness is obtained. The composition migrates very soon after one hour. The composition also has good color fastness (Samba chromasphere test).
[0102] EXAMPLE 4 The following composition is prepared (contents expressed as% by weight of active ingredient, unless otherwise indicated); 3037794 52 Phase Ingredients content A Ethylcellulose (dispersion in water - 30% solids, containing ethylcellulose, sodium lauryl sulfate, cetyl alcohol, AQUACOAT ECD 30 from FMC Biopolymer) 31.3 A Copolymer Styrene / Methyl Styrene / Hydrogenated Indene (REGALITE R1100 CG Hydrocarbon Resin, Eastman) 78 A Octyldodecanol 13.2 B1 Sorbitan Stearate - Sucrose Cocoate (ARLACEL 2121 U-FL, Croda) 3.8 B2 Hydroxypropyl guar (Jaguar HP 105 - Solvay) 0.2 A Neopentyl glycol dicaprate (ESTEMOL N-01; Nisshin Oillio) 117 F Trimethylsiloxyphenyl dimethicone (BELSIL® PDM 1000; Wacker) 219 G1 Yellow 6 0.22 G1 Red 33 0.04 G1 Water qs 100 G2 Red 7 0.5 H Preservative 0.7 H Ethanol 96 ° 3.3 Procedure The procedure is as for the preceding example, the neopentylglycol dicaprate being introduced with the hydrocarbon resin and octyldodecanol.
[0103] A homogeneous, stable and fluid composition is obtained. The application of the composition on the lips is easy and one obtains a comfortable deposit, of homogeneous thickness, brilliant and covering. The composition migrates very soon after one hour.
[0104] The composition also has good color fastness (Samba chromasphere test). EXAMPLE 5 The following composition is prepared (contents expressed in% by weight of active material, unless otherwise indicated): Phase Ingredients Content A Ethylcellulose (dispersion in water - 30% dry matter, 31.3% 3037794%) ethylcellulose, sodium lauryl sulfate, cetyl alcohol, AQUACOAT ECD 30 from FMC Biopolymer) A 'Octyldodecanol 20 A' Hydrogenated Styrene / Methyl Styrene / Indene Copolymer (REGALITE R1100 CG Hydrocarbon Resin, Eastman) 7.8 B1 Stearate sorbitan - sucrose cocoate (ARLACEL 2121 U-FL, Croda) B2 Hydroxypropyl guar (Jaguar HP 105, Solvay) 0.2 A Polybutene (Indopol H 100, INEOS) 5 F Trimethylsiloxyphenyl dimethicone (BELSIL® PDM 1000; Wacker) 21 9 G1 Red 33 0.04 G1 Water qs 100 G2 Red 7 0.5 H Preservative 0.7 H Ethanol 96 ° 3.3 Procedure The procedure is as for the preceding example, the polybutene being introduced with the hydrocarbon resin and octyldodecanol.
[0105] A homogeneous, stable and fluid composition is obtained. The application of the composition on the lips is easy and one obtains a comfortable deposit, of homogeneous thickness, brilliant and covering. The composition migrates very soon after one hour.
[0106] The composition also has good color fastness (Samba chromasphere test).

权利要求:
Claims (20)
[0001]
REVENDICATIONS1. Cosmetic composition in the form of an emulsion comprising: (A) at least 5% by weight of water relative to the total weight of the composition; (B) alkylcellulose, the alkyl residue of which has 2 to 6 carbon atoms; preferably ethylcellulose; (C) at least one hydrocarbon, fluorinated or non-volatile silicone oil; (D) at least one hydrocarbon resin of average molecular weight less than or equal to 10,000 g / mol. 10
[0002]
2. Composition according to the preceding claim, characterized in that the alkylcellulose is present in a content ranging from 1 to 20% by weight, preferably from 4 to 20% by weight, more preferably from 5 to 15% by weight, relative to total weight of the composition. 15
[0003]
3. Composition according to any one of the preceding claims, characterized in that the composition comprises at least a first non-volatile hydrocarbon oil chosen from: lauric alcohol, isostearyl alcohol, oleic alcohol, 2-hexyldecyl alcohol, alcohol isocetyl, octyldodecanol and mixtures thereof; Monoesters, optionally hydroxylated, of a C 2 -C 8 carboxylic acid and of a C 2 -C 8 alcohol; diester, optionally hydroxylated, of a C2-C8 dicarboxylic acid and of a C2-C8 alcohol, such as diisopropyl adipate, 2-diethylhexyl adipate, dibutyl adipate, or diisostearyl adipate; Optionally hydroxy triesters of a C2-C8 triacid and a C2-C8 alcohol, such as citric acid esters, such as trioctyl citrate, triethyl citrate, acetyl tributyl citrate, tributyl; citrate; esters of a C2-C8 polyol and of one or more C2-C8 carboxylic acids, such as glycol and monoacid diesters, such as neopentyl glycol diheptanoate, or glycol and monoacid triesters; such as triacetin.
[0004]
4. Composition according to the preceding claim, characterized in that the first or non-volatile hydrocarbon oils are chosen from C 10 -C 26 alcohols, preferably monoalcohols, preferably chosen from lauryl alcohol, isostearyl alcohol and oleic alcohol. 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol and mixtures thereof, preferably octyldodecanol.
[0005]
5. Composition according to any one of claims 3 or 4, characterized in that the first non-volatile hydrocarbon oil or oils are present in a content ranging from 5% to 50%, in particular from 10% to 35% by weight. weight, relative to the total weight of the composition.
[0006]
6. Composition according to any one of the preceding claims, characterized in that the composition comprises at least one non-volatile silicone oil, phenylated or non-phenylated, preferably chosen from phenyltrimethicones, phenyldimethicones, phenyltrimethylsiloxy diphenylsiloxanes, tetramethyltetraphenyl trisiloxanes, phenyltrimethylsiloxytrisiloxane, diphenylsiloxyphenyl trimethicones, diphenyldimethicones, diphenylmethyldiphenyltrisiloxanes, trimethylsiloxyphenyl dimethicones, triphenyl trimethicones, trimethyl pentaphenyl trisiloxanes, and mixtures thereof.
[0007]
7. Composition according to any one of the preceding claims, characterized in that the content of non-volatile oil (s) silicone (s) represents from 5 to 75% by weight, in particular from 5 to 60% by weight. and preferably from 10 to 50% by weight, based on the weight of the composition.
[0008]
8. Composition according to any one of the preceding claims, characterized in that the composition comprises, as hydrocarbon oil, at least one second non-volatile polar hydrocarbon oil, different from the first oil or oils, the polar oil or oils being preferably chosen from: ester oils having at least 18 carbon atoms, especially: monoesters comprising at least 18 carbon atoms, fatty acid monoesters comprising at least 18 carbon atoms and diol diesters comprising at least 17 carbon atoms * hydroxyl monoesters and diesters comprising at least 18 carbon atoms * triesters comprising at least 35 carbon atoms * tetraesters comprising at least 35 carbon atoms * polyesters obtained by condensation of dimer and and / or trimer of unsaturated fatty acid and diol * the esters and polyesters of diol dimer and mono- or dicarboxylic acid * polyesters r resulting from the esterification of at least one carboxylic acid (s) triglyceride (s) hydroxylated by an aliphatic monocarboxylic acid and an aliphatic dicarboxylic acid, optionally unsaturated * vegetable hydrocarbon oils * sucrose esters - oils comprising at least one carbonate function - their mixtures; Preferably at a content ranging from 1 to 35% by weight of second (s) non-volatile hydrocarbon oil (s) polar (s) polar (s), in particular from 5 to 20% by weight, relative to to the total weight of the composition. 5
[0009]
9. Composition according to any one of the preceding claims, characterized in that it comprises as hydrocarbon oil, at least one second apolar non-volatile hydrocarbon oil chosen from: - paraffin oil or its derivatives, - the squalane,
[0010]
Isoeicosane, naphthalene oil, hydrogenated or non-hydrogenated polybutenes, polyisobutenes, whether or not hydrogenated, polydecenes, whether or not hydrogenated, decene / butene copolymers, polybutene / polyisobutene copolymers, their mixtures, at a content preferably ranging from 1 to 75% by weight of second non-volatile hydrocarbon-based non-volatile oil (s), in particular from 1 to 60% by weight, and more particularly from 1 to 35% by weight, relative to the total weight of the composition. 10. Composition according to any one of the preceding claims, characterized in that it comprises at least one fluorinated oil chosen from fluorosilicone oils, fluorinated polyethers, fluorinated silicones, perfluorinated compounds, alone or in mixtures; preferably at a content ranging from 1 to 75% by weight, more particularly from 1 to 40% by weight, preferably from 1 to 20% by weight, relative to the weight of the composition.
[0011]
11. Composition according to any one of the preceding claims, characterized in that it comprises at least a first non-volatile hydrocarbon oil and at least one additional oil chosen from silicone oils, fluorinated oils and second non-volatile hydrocarbon oils. , polar or apolar, as well as their mixtures.
[0012]
12. Composition according to any one of the preceding claims, characterized in that it comprises from 5% to 80% by weight of water, preferably from 10% to 70% by weight, in particular from 15% to 60% by weight. % by weight, and more preferably from 20% to 50%, by weight, based on its total weight.
[0013]
13. Composition according to any one of the preceding claims, characterized in that the hydrocarbon resin is chosen from: hydrogenated indene / methylstyrene / styrene copolymers; aliphatic pentanediene resins; diene resins of dimers of cyclopentanediene; the hydrogenated resins resulting from the polymerization of pentanediene; And mixtures thereof and preferably hydrogenated indene / methylstyrene / styrene copolymers.
[0014]
14. Composition according to any one of the preceding claims wherein the resin content is from 2% to 20% by weight, preferably from 2% to 18% by weight, relative to the total weight of the composition.
[0015]
15. Composition according to any one of the preceding claims, characterized in that the composition comprises at least one C2-C8 polyol, preferably C3-C6, saturated or unsaturated, linear or branched, comprising from 2 to 6 groups. hydroxyl, and preferably glycerine, propylene glycol, 1,3-butylene glycol, dipropylene glycol, diglycerine, and mixtures thereof; preferably at a content ranging from 0.1 to 20% by weight, preferably from 1 to 10% by weight, and more particularly from 2 to 6% by weight, relative to the weight of the composition. 20
[0016]
16. Composition according to any one of the preceding claims, characterized in that it comprises at least one anionic surfactant, preferably chosen from alkali metal alkyl sulphate and alkyl ether sulphates, having at least 12 carbon atoms, more particularly from 12 to 16 carbon atoms, and optionally comprising from 1 to 20 oxyethylenated units and mixtures thereof; preferably anionic surfactant content is 0.1 to 2% by weight, preferably 0.2 to 1.5% by weight, based on the weight of the composition
[0017]
17. Composition according to any one of the preceding claims, characterized in that it comprises at least one nonionic surfactant, preferably selected from alkyl and polyalkyl esters of sorbitan, preferably non-polyoxyethylenated; fatty alcohols, having at least 8 carbon atoms, and may contain from 1 to 150 oxyethylene and / or oxypropylene units; their mixtures; preferably at a content ranging from 0.5 to 10% by weight, preferably from 1 to 5% by weight, relative to the weight of the composition. 35
[0018]
18. Composition according to any one of the preceding claims, characterized in that it comprises at least one dyestuff. 3037794 58
[0019]
19. Composition according to any one of the preceding claims, characterized in that the said composition is a make-up and / or care composition for keratin materials, in particular lips. 5
[0020]
20. A cosmetic process for making up and / or caring for keratin materials, in particular the lips, comprising at least one step consisting in applying to said keratinous materials at least one composition as defined according to any one of the preceding claims.

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同族专利:

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公开号 | 公开日

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KR20180011268A|2018-01-31|

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US20180140515A1|2018-05-24|

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FR3037794B1|2017-07-07|

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JP2018518493A|2018-07-12|

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WO2016207349A1|2016-12-29|

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EP3313359A1|2018-05-02|

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CN107787221A|2018-03-09|

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FR2964868A1|2010-09-20|2012-03-23|Oreal|Composition, useful for make up and/or care lips/skin, preferably lipstick, comprises water, alkylcellulose, a first non-volatile hydrocarbon oil e.g. monoalcohol, a second non-volatile oil e.g. silicone oil and a stabilizing agent|

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2021-03-12| ST| Notification of lapse|Effective date: 20210205 |

优先权:

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申请号 | 申请日 | 专利标题

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FR1555981A|FR3037794B1|2015-06-26|2015-06-26|AQUEOUS COSMETIC COMPOSITION COMPRISING ALKYLCELLULOSE, AT LEAST ONE NON-VOLATILE OIL, A HYDROCARBONATED RESIN|FR1555981A| FR3037794B1|2015-06-26|2015-06-26|AQUEOUS COSMETIC COMPOSITION COMPRISING ALKYLCELLULOSE, AT LEAST ONE NON-VOLATILE OIL, A HYDROCARBONATED RESIN|

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US15/578,302| US20180140515A1|2015-06-26|2016-06-24|Aqueous cosmetic composition comprising alkylcellulose, at least one non-volatile oil and a hydrocarbon-based resin|

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CN201680037588.5A| CN107787221A|2015-06-26|2016-06-24|Include the aqueous cosmetic composition of alkylcellulose, at least one nonvolatile oil and resin based on hydrocarbon|

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EP16732592.7A| EP3313359A1|2015-06-26|2016-06-24|Aqueous cosmetic composition comprising alkylcellulose, at least one non-volatile oil and a hydrocarbon-based resin|

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PCT/EP2016/064663| WO2016207349A1|2015-06-26|2016-06-24|Aqueous cosmetic composition comprising alkylcellulose, at least one non-volatile oil and a hydrocarbon-based resin|

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JP2017565269A| JP2018518493A|2015-06-26|2016-06-24|Aqueous cosmetic composition comprising alkylcellulose, at least one non-volatile oil and a hydrocarbon resin|

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KR1020177037512A| KR20180011268A|2015-06-26|2016-06-24|Aqueous cosmetic composition comprising alkylcellulose, at least one non-volatile oil and a hydrocarbon-based resin|